Basic Achievements in the Coordination Chemistry of Modified Monosaccharides

Abstract

Organic chemistryOrganic chemistry Z 0200 Basic Achievements in the Coordination Chemistry of Modified Monosaccharides -[155 refs.]. -(ZHDANOV, Y. A.; ALEKSEEV, Y. E.; Russ. Chem. Rev. (Engl. Transl.) 71 (2002) 11, 969-980; Inst. Phys. Org. Chem., Rostov State Univ., Rostov-on-Don 344090, Russia; Eng.) -Lindner 20-260

Regioselective Benzoylation of Glycopyranosides by Benzoyl Chloride in the Presence of MoO2(acac)2

“…[29][30][31] It can be assumed that the nucleophilicity of complexed hydroxyl groups will depend on metal as well as the geometry of intermediate complexes. Thus, the complexation of carbohydrates may increase discrimination of reactivity of hydroxyl groups in nucleophilic reactions.…”