2023
DOI: 10.1016/j.marpetgeo.2023.106180
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Basin and petroleum systems modelling to characterise multi-source hydrocarbon generation: A case study on the inner Moray Firth, UK North Sea

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Cited by 9 publications
(10 citation statements)
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“…Generally, hydrocarbons produce reductive environments leading to the formation of iron sulphides (Machel, 1995; Zhang et al., 2018), however, in very low‐sulfur hydrocarbon environments, magnetite formation has been widely observed and reported (e.g., Perkins, 2022). Perkins (2022) suggests that the magnetite is formed in relatively small quantities during the dehydroxylation of goethite to hematite, however, given magnetite's relatively strong magnetic properties, it dominates the NRM.…”
Section: Discussionmentioning
confidence: 99%
See 1 more Smart Citation
“…Generally, hydrocarbons produce reductive environments leading to the formation of iron sulphides (Machel, 1995; Zhang et al., 2018), however, in very low‐sulfur hydrocarbon environments, magnetite formation has been widely observed and reported (e.g., Perkins, 2022). Perkins (2022) suggests that the magnetite is formed in relatively small quantities during the dehydroxylation of goethite to hematite, however, given magnetite's relatively strong magnetic properties, it dominates the NRM.…”
Section: Discussionmentioning
confidence: 99%
“…The chemical processes leading to magnetic mineral formation in the presence of hydrocarbons is complex, and depends on the complex interplay between the host reservoir rocks, sulfur content of the hydrocarbons, origin of the hydrocarbons, the redox conditions and temperature/depth of remagnetization (Abdulkarim et al., 2022; Badejo et al., 2021; Machel, 1995; Perkins, 2022). Generally, hydrocarbons produce reductive environments leading to the formation of iron sulphides (Machel, 1995; Zhang et al., 2018), however, in very low‐sulfur hydrocarbon environments, magnetite formation has been widely observed and reported (e.g., Perkins, 2022). Perkins (2022) suggests that the magnetite is formed in relatively small quantities during the dehydroxylation of goethite to hematite, however, given magnetite's relatively strong magnetic properties, it dominates the NRM.…”
Section: Discussionmentioning
confidence: 99%
“…Maghemite is also commonly found in the presence of additional non-magnetic minerals that form magnetite during HT-χ analysis (Oches and Banerjee, 1996). We provide an example of maghemite HT-χ behaviour, in the presence of magnetite, in Figure 1B; the sample is obtained from the sandstone interval of the Pentland Formation from the Inner Moray Firth, North Sea (Perkins, 2022;Perkins et al, 2023). Maghemite inverts to hematite on heating, leading to a drop in susceptibility as the spontaneous magnetisation of maghemite is ∼ 150× greater than that of hematite Dunlop and Özdemir (1997).…”
Section: Iron Oxidesmentioning
confidence: 99%
“…In Figure 1B, at temperatures >500 °C, there is a secondary peak. This secondary peak is likely a combination of two processes: 1) the formation and presence of magnetite, FIGURE 1 HT-χ data for (A) the magnetite (Fe 3 O 4 sample described in Muxworthy, 1998;Muxworthy and McClelland, 2000); (B) maghemite (γ-Fe 2 O 3 ) from Well 12/27-1 (depth 3,738.9 ft) in the Inner Moray Firth, North Sea (Perkins, 2022;Perkins et al, 2023); and (C) hematite (α-Fe 2 O 3 , unpublished). In (B), some magnetite formation observed during the experiment is shown.…”
Section: Iron Oxidesmentioning
confidence: 99%
“…In addition to the spatial distribution and geochemistry, the thermal maturity and gas generation of the source rocks are essential for shale gas accumulation. Basin modeling provides an important means to quantitatively simulate the tectonic evolution, thermal maturity, hydrocarbon generation, and expulsion history of source rocks and hydrocarbon migration and accumulation. The thermal history and maturity of the Shanxi Formation shale have been tentatively simulated using a one-dimensional (1D) basin model, , but this model has left gaps in understanding the three-dimensional (3D) burial, thermal evolution, and hydrocarbon generation history of the source rock.…”
Section: Introductionmentioning
confidence: 99%