Batch-screening guided continuous flow synthesis of the metal-organic framework HKUST-1 in a millifluidic droplet reactor

Shukre, Rajasi; Ericson, Thomas; Unruh, Daniel K.; Harbin, Hannah; Cozzolino, Anthony F.; Chen, Chau‐Chyun; Vanapalli, Siva A.

doi:10.1016/j.micromeso.2022.112005

Cited by 6 publications

(1 citation statement)

References 69 publications

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“…Plug flow reactors are commonly used in chemical engineering for processes requiring controlled residence times and uniform reaction conditions. 70 Combining the advantages of traditional batch reactors with the principles of flow chemistry, stirred flow reactors enhance mixing and mass transfer while maintaining continuous flow. 71 Paseta and coworkers 72 indicated that there is an inverse relationship between the crystallite size and size distribution, and the factors of residence time, temperature, and slug volume.…”

Section: Fe-based Mof Structures Synthesized Via Different Routesmentioning

confidence: 99%

Recent trends on MIL-Fe metal–organic frameworks: synthesis approaches, structural insights, and applications in organic pollutant adsorption and photocatalytic degradation

Channab,

El Ouardi,

Ait Layachi

et al. 2023

Environ. Sci.: Nano

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Section: Fe-based Mof Structures Synthesized Via Different Routesmentioning

confidence: 99%

Recent trends on MIL-Fe metal–organic frameworks: synthesis approaches, structural insights, and applications in organic pollutant adsorption and photocatalytic degradation

Channab,

El Ouardi,

Ait Layachi

et al. 2023

Environ. Sci.: Nano

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Machine Learning and Digital Manufacturing Approaches for Solid‐State Materials Development

Glasby¹,

Whaites²,

Moghadam³

2023

AI‐Guided Design and Property Prediction for Zeolites and Nanoporous Materials

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Continuous and Scalable Synthesis of Prussian Blue Analogues with Tunable Structure and Composition in Surfactant‐Free Microreactor for Stable Zinc‐Ion Storage

Wang,

Ma,

et al. 2024

ChemSusChem

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We represent a segmented flow surfactant‐free microfluidic strategy for continuous synthesis of Prussian blue analogues (PBAs) with high dispersity and high crystallization. Representative zinc hexacyanoferrate (ZnHCF) nanocubes were successfully synthesized in a microfluidic reactor within a few minutes via the cooperation method and possessed lower contents of crystal water and Fe(CN)63‐ vacancies than that of synthesis in bulk solution. The nucleation and particle growth process can be precisely controlled by the exploration of different flow rates and reaction temperatures during the formation of ZnHCF nanocubes in segmented flow microfluidic reactors. High crystallinity, low crystal water and vacancies in the ZnHCF structure were presented at relatively high temperatures for the crystal growth process. High‐quality ZnHCF with a low content of crystal water showed excellent electrochemical activity and stability towards zinc‐ion storage. The continuous and scalable synthesis approach can be extended to the fabrication of other PBAs such as NiHCF, CoHCF, MnHCF, and CuHCF with high dispersity without using any surfactants. The controllable construction of PBAs with tunable properties in microfluidic reactors provides a promising direction to minimize the gap between commercial reality and laboratory research.

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Batch-screening guided continuous flow synthesis of the metal-organic framework HKUST-1 in a millifluidic droplet reactor

Cited by 6 publications

References 69 publications

Recent trends on MIL-Fe metal–organic frameworks: synthesis approaches, structural insights, and applications in organic pollutant adsorption and photocatalytic degradation

Recent trends on MIL-Fe metal–organic frameworks: synthesis approaches, structural insights, and applications in organic pollutant adsorption and photocatalytic degradation

Machine Learning and Digital Manufacturing Approaches for Solid‐State Materials Development

Continuous and Scalable Synthesis of Prussian Blue Analogues with Tunable Structure and Composition in Surfactant‐Free Microreactor for Stable Zinc‐Ion Storage

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