Passive Internet-of-Things (IoT), a new paradigm based on battery-free devices, is a promising technology to enable several use cases that require connectivity with stringent requirements in terms of cost, complexity, and energy efficiency. These use cases span critical sectors, such as healthcare, transportation, and agriculture. Passive IoT relies on the development of technologies such as radio frequency (RF) energy harvesting, low-power computing, and backscatter communication. Particularly, backscatter communication allows devices to modulate its information on external RF signals that are backscattered to the receiver or reader.BC considers the following elements: a carrier emitter (CE), a reader, and a backscatter device (BD). The main BC configurations are monostatic BC (MoBC), ambient BC (AmBC) and bistatic BC (BiBC). In a MoBC setup, the CE and reader are co-located and share parts of the same infrastructure. A monostatic system suffers from round-trip path loss, and requires full-duplex technology if the same antennas are simultaneously used for transmission and reception. In an AmBC setup, CE and reader are in different locations, while the CE is not considered dedicated. AmBC uses ambient sources to transmit information, such as Wi-Fi, Bluetooth, and TV signals. In BiBC, the CE and reader are also spatially separated from each other, but there is a dedicated CE. In addition, BiBC can operate in half duplex mode, thus avoiding the complexity associated to the full-duplex operation.Due to the double path-loss effect on the two-way backscatter link, the received backscattered signal is typically weak compared to the direct link interference (DLI) from a CE. This requires a high dynamic range of the circuitry in the reader. As a result, a high-resolution analog-to-digital converter (ADC) is required to detect the weak backscattered signal under heavy DLI; this represents a great limitation because ADCs are major power consumers. Nonetheless, the benefits provided by multiple-antenna and distributed multiple-input multiple-output (MIMO) technologies can be explored to circumvent the limitations of BiBC, which is the main focus of this thesis.