BEDT-TTF-based radical cation salt with the cyanurate anion: synthesis, structure, conductivity, and polarized reflection spectra

Abstract

The new conducting radical cation salt, bis(ethylenedithio)tetrathiafulvalene cyanurate, was synthesized. This salt is an organic metal down to 4 K. The crystal structure, conductivity, and optical properties of the salt were studied.

Hydrogen-Bonded Anionic Host Lattices Constructed with Isocyanurate and Thiourea/Urea

“…Generation of the mono-, di-, and trianionic forms at p K a values of 6.85, 10.91, and >12, respectively, was reported by Aoki et al in 2000 . Surprisingly, to date only 12 single-crystal X-ray structures of hydrogen-bonded complexes of the ordered isocyanurate ion are documented in the Cambridge Structural Database, CSD V5.36 (November, 2014) with May 2015 update. − …”