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Purpose: The objective of this work was to evaluate the thermal insulation performance of lightweight geopolymer concretes with expanded clay, considering their implications for energy consumption and construction efficiency. Theoretical framework: The urgent need for sustainable construction practices amid global concerns about climate change and environmental degradation has been increasingly discussed. With the cement industry being a major contributor to CO2 emissions, alternative materials like geopolymers offer a promising solution, once the consumption of concrete tends to grow bigger. The production of geopolymer concrete, known for its strength and low environmental impact, involves combining a precursor rich in aluminosilicates with an alkaline activator, usually sodium hydroxide and sodium silicate. Notably, geopolymer cement can cut up to 64% of greenhouse gas emissions. Expanded clay, as a lightweight aggregate, garners attention for its porous structure and ability to provide thermal and acoustic insulation to concrete. Its application in constructing vertical enclosures, such as concrete walls, enhances thermoacoustic comfort and aids in assembly and transportation on construction sites. Effective thermal insulation, achieved through materials with low thermal conductivity, plays a pivotal role in creating thermally suitable environments, impacting user satisfaction, productivity, and energy conservation. Method and materials: The materials used for concrete production, including metakaolin, sodium hydroxide, sodium silicate, expanded clay, crushed stone, and sand, were initially characterized. Subsequently, the dosage calculation for the production of test specimens was performed, involving mini concrete slabs with dimensions of 20x40x12 cm, compacted on a vibrating table. The concretes were produced with volume substitutions of crushed stone by expanded clay at 0% (GP) 30% (GP30%) and 70% (GP70%). For the thermal insulation test, the slabs were exposed to a heat source, and temperatures on the exposed and opposite faces were measured over 12 hours, at 30-minute intervals. After obtaining the experimental data, logarithmic equations with three parameters were fitted to achieve the stabilization temperature of the surfaces. Results and conclusion: Despite the expectation of stabilization in temperature after exposure to a heat source, it was not observed for the faces of the tested panels. A mathematical curve was derived through a curve-fitting process using logarithmic equations with three parameters. All curve fittings yielded R² values equal to or higher than 0.95, indicating satisfactory representativity and suggesting viability in analyzing panel thermal insulation through the adjusted equations. Considering the adjusted data, thermal insulation values for GP, GP30%, and GP70% were 31.82 °C, 35.30 °C, and 40.24 °C, respectively. Expanded clay's effect on increasing thermal insulation was evident, aligning with references indicating its insulating characteristics. Moreover, the substitution of crushed stone with expanded clay led to a noticeable reduction in specific mass, highlighting the lightweight nature of the compositions. Both 30% and 70% mixes fall under the lightweight category. Research implications: To produce a more environmentally friendly concrete using geopolymer cement, combined with expanded clay, aiming for a weight reduction in precast concrete wall structures and an improvement in the thermal insulation of these systems. Originality/value: To assess the feasibility of using lightweight geopolymer concretes with locally sourced materials through tests conducted in Brazilian studies, aiming to contribute to the existing gap in knowledge regarding the behavior of this alternative binder.
Purpose: The objective of this work was to evaluate the thermal insulation performance of lightweight geopolymer concretes with expanded clay, considering their implications for energy consumption and construction efficiency. Theoretical framework: The urgent need for sustainable construction practices amid global concerns about climate change and environmental degradation has been increasingly discussed. With the cement industry being a major contributor to CO2 emissions, alternative materials like geopolymers offer a promising solution, once the consumption of concrete tends to grow bigger. The production of geopolymer concrete, known for its strength and low environmental impact, involves combining a precursor rich in aluminosilicates with an alkaline activator, usually sodium hydroxide and sodium silicate. Notably, geopolymer cement can cut up to 64% of greenhouse gas emissions. Expanded clay, as a lightweight aggregate, garners attention for its porous structure and ability to provide thermal and acoustic insulation to concrete. Its application in constructing vertical enclosures, such as concrete walls, enhances thermoacoustic comfort and aids in assembly and transportation on construction sites. Effective thermal insulation, achieved through materials with low thermal conductivity, plays a pivotal role in creating thermally suitable environments, impacting user satisfaction, productivity, and energy conservation. Method and materials: The materials used for concrete production, including metakaolin, sodium hydroxide, sodium silicate, expanded clay, crushed stone, and sand, were initially characterized. Subsequently, the dosage calculation for the production of test specimens was performed, involving mini concrete slabs with dimensions of 20x40x12 cm, compacted on a vibrating table. The concretes were produced with volume substitutions of crushed stone by expanded clay at 0% (GP) 30% (GP30%) and 70% (GP70%). For the thermal insulation test, the slabs were exposed to a heat source, and temperatures on the exposed and opposite faces were measured over 12 hours, at 30-minute intervals. After obtaining the experimental data, logarithmic equations with three parameters were fitted to achieve the stabilization temperature of the surfaces. Results and conclusion: Despite the expectation of stabilization in temperature after exposure to a heat source, it was not observed for the faces of the tested panels. A mathematical curve was derived through a curve-fitting process using logarithmic equations with three parameters. All curve fittings yielded R² values equal to or higher than 0.95, indicating satisfactory representativity and suggesting viability in analyzing panel thermal insulation through the adjusted equations. Considering the adjusted data, thermal insulation values for GP, GP30%, and GP70% were 31.82 °C, 35.30 °C, and 40.24 °C, respectively. Expanded clay's effect on increasing thermal insulation was evident, aligning with references indicating its insulating characteristics. Moreover, the substitution of crushed stone with expanded clay led to a noticeable reduction in specific mass, highlighting the lightweight nature of the compositions. Both 30% and 70% mixes fall under the lightweight category. Research implications: To produce a more environmentally friendly concrete using geopolymer cement, combined with expanded clay, aiming for a weight reduction in precast concrete wall structures and an improvement in the thermal insulation of these systems. Originality/value: To assess the feasibility of using lightweight geopolymer concretes with locally sourced materials through tests conducted in Brazilian studies, aiming to contribute to the existing gap in knowledge regarding the behavior of this alternative binder.
Purpose: This study aims to investigate the valorisation of sludge from Leather Tannery Wastewater Treatment Plants (LTWWTP) by incorporating it into cement mortars. Theoretical framework: The substantial quantity of waste generated by industries coupled with the scarcity of natural resources calls for the analysis, development, and implementation of treatment methods to recover and reuse materials, thereby minimising the environmental impact of waste disposal. The leather tanning industry, a significant polluter due to its use of hazardous and heavy materials, requires sustainable solutions for waste management. One promising approach is the incorporation of waste into cementitious matrices. Method: Three scenarios were examined: low-moisture sludge, ash obtained via incineration, and wet oxidation. Test specimens were prepared with varying proportions of cement replacement (0, 3, 5, 7, and 10%), and their flexural and compressive strengths were evaluated. Additionally, chemical analyses were conducted to assess solubility. Results and Conclusion: The results indicate that sludge can be used in small proportions without compromising the mechanical strength of the mortar. Substituting 10% cement with ash using the INC-2 incineration method improved mortar quality, exhibiting a higher compressive strength of 41 MPa and minimal water absorption (3.28%). Research implications: Drawing from these promising findings, it can be confidently asserted that utilising WWTP sludge in mortar is a practical, eco-conscious solution for civil construction. Furthermore, it is a pivotal step towards addressing the challenge of hazardous sludge disposal. Originality/value: The findings from this research will contribute to sustainable waste management practices and pave the way for responsible and eco-friendly utilisation of industrial waste in cementitious materials, thus minimising environmental burdens.
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