Beitr�ge zur Chemie des Thalliums und Arsens

Vanadium(III) Sulfate as a Reducing Agent for Determination of Perchlorate.

“…has been reported (10) which has a vanadium content 9401, that of pure V2(S0&.] The product obtained in the above preparation is more soluble than pure Vz(SOa)3 and therefore is preferred for perchlorate reduction.…”

“…Russell has also suggested as the product formed during basecatalyzed reactions of 02 with organic mono-and dianions in DMSO (H). Superoxide salts have also been found as one of the products of electrolytic oxygen reduction in liquid ammonia (10). This paper reports the detailed investigation of the electrolytic reduction of oxygen in aprotic organic solvents.…”

“…It is very unlikely that any reduction involving the consumption of protons would occur reversibly in a solvent with such low proton availability; therefore, it was concluded that the usual 2-electron reduction to HOz-was not operative. Superoxide salts have also been found as one of the products of electrolytic oxygen reduction in liquid ammonia (10). This paper reports the detailed investigation of the electrolytic reduction of oxygen in aprotic organic solvents.…”