Benchmark Study of Hydrogen Storage in Metal–Organic Frameworks under Temperature and Pressure Swing Conditions

Abstract

lett.8b00154. Details on experimental and computational methods as well as adsorption isotherms, isosteric heats of adsorption, and PXRD patterns (PDF)■ AUTHOR INFORMATION

Boron‐ and nitrogen‐doped penta‐graphene as a promising material for hydrogen storage: A computational study

“…The US Department of Energy (DOE) challenged scientists to achieve onboard vehicle H 2 storage systems in 2020 (4.5 wt%) and 2025 (5.5 wt%) and achievable (6.5 wt%) targets for onboard hydrogen storage equipment to be used in light-duty vehicles. 10 Carbon-based nanomaterials 8,[11][12][13][14][15] such as graphene, 3,16 graphite, graphite nanofibers, carbon nanotubes, fullerenes, metal-organic frameworks (MOFs), and covalent-organic frameworks (COFs) [17][18][19][20] have been examined as potential H 2 storage materials because of their chemical stability, large specific surface area, and lightweight. In general, researchers use two different successful hydrogen storage forms: atomic (through chemical adsorption) and molecular forms (through physical adsorption).…”

“…There are strict requirements in ideal materials for H 2 storage practical applications. The US Department of Energy (DOE) challenged scientists to achieve onboard vehicle H 2 storage systems in 2020 (4.5 wt%) and 2025 (5.5 wt%) and achievable (6.5 wt%) targets for onboard hydrogen storage equipment to be used in light‐duty vehicles …”

Enhanced Crystallization and Optimized Morphology of Perovskites Through Doping an Indium‐Based Metal–Organic Assembly: Achieving Significant Solar Cell Efficiency Enhancements

“…During the past few years, metal–organic assembly has attracted increasing interest due to the potential applications in gas storage, catalysis, photoluminescence sensor, and drug delivery . Very recently, a metal–organic assembly has also shown the potential to be applied in PSCs.…”

Engineering MIL‐88B crystallites for enhanced H 2 uptake capacity: The role of ultramicropores

“…In 1995, a new family of porous materials, MOFs, formed of an organic and inorganic part was introduced . Controllable synthesis conditions, designable organic ligands, tuneable pore sizes, high specific surface area, and the highly porous nature make MOFs attractive in H 2 storage applications …”

“…18 Controllable synthesis conditions, designable organic ligands, tuneable pore sizes, high specific surface area, and the highly porous nature make MOFs attractive in H 2 storage applications. 5,14,[19][20][21] MOFs possess incredibly high H 2 adsorption capacities at high pressures and cryogenic temperatures. 5,[22][23][24] However, very low H 2 sorption capacities can be achieved at 298 K and low pressures.…”