2013
DOI: 10.1063/1.4800446
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Bending stress induced improved chemiresistive gas sensing characteristics of flexible cobalt-phthalocyanine thin films

Abstract: We report chemiresistive gas sensing characteristics of cobalt phthalocyanine films deposited on flexible bi-axially oriented polyethylene terephthalate substrates. Charge carrier mobility in these films systematically decreases upon bending, which implies that bending reduces π-π interactions among molecules. At room temperature, these films exhibited a reversible change in resistance on exposure to ammonia (5–50 ppm) along with high sensitivity and selectivity as well as fast response and recovery. The chemi… Show more

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Cited by 40 publications
(27 citation statements)
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“…At higher bending angle, the average distance between film and the analytes increases leading to a lower sensitivity of the film. Similar increase in the sensitivity of the sensor with the bending angle is being reported by other groups4445.…”
Section: Discussionsupporting
confidence: 89%
“…At higher bending angle, the average distance between film and the analytes increases leading to a lower sensitivity of the film. Similar increase in the sensitivity of the sensor with the bending angle is being reported by other groups4445.…”
Section: Discussionsupporting
confidence: 89%
“…An ideal sensor should meet the following significant criteria: i) operation at room temperature in an ambient environment; ii) fast response and recovery times without an external stimulus (e.g. UV lamp); iii) high sensitivity with a low detection limit; iv) high reproducibility with repeatable responses; v) cost effective and easy‐to‐fabricate; vi) low‐voltage (<5 V) power design; and vii) biocompatible and eco‐friendly …”
Section: Nanomaterial‐based Flexible Sensors For Volatolomic Applicatmentioning
confidence: 99%
“…These films showed high mobility and exhibited enhanced sensitivity towards ammonia on bending which shows its potential for ammonia sensor at curved surfaces 15,16. These devices were stable for 70 days under atmospheric conditions.…”
mentioning
confidence: 93%
“…[13][14][15][16][17] In-situ photopolymerisation of pyrrole using AgNO 3 as photosensitizer on modified BOPET substrate resulted in adhesive and flexible PPy-Ag nanocomposites films. [13][14][15][16][17] In-situ photopolymerisation of pyrrole using AgNO 3 as photosensitizer on modified BOPET substrate resulted in adhesive and flexible PPy-Ag nanocomposites films.…”
Section: Introductionmentioning
confidence: 99%