The decay properties of the linear-chain states in 14 C are investigated by using antisymmetrized molecular dynamics. The calculation predicts two rotational bands with linear-chain configurations having the π -bond and σ -bond valence neutrons. For the π -bond linear-chain, the calculated excitation energies and the widths of α-decay to the ground state of 10 Be reasonably agree with the experimental candidates observed by the α + 10 Be resonant scattering. On the other hand, the σ -bond linear-chain is the candidate of the higher-lying resonant states reported by the breakup reaction. As the evidence of the σ -bond linear chain, we discuss its decay pattern. It is found that the σ -bond linear chain not only decays to the excited band of 10 Be but also decays to the three-body channel of 6 He + α + α, and the branching ratio of these decays are comparable. Hence, we suggest that this characteristic decay pattern is a strong signature of the linear-chain formation and a key observable to distinguish two different linear chains.