1956
DOI: 10.1021/ja01602a002
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Benzenethiol: Thermodynamic Properties in the Solid, Liquid and Vapor States; Internal Rotation of the Thiol Group1

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Cited by 78 publications
(39 citation statements)
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“…The spectral changes are at- tributed to adsorption modes of the compound at the silver and iron surfaces. Fu~her details and tentative assignments (16,18) of the bands in the Raman and SERS spectra of benzenethiol are tabulated in Table II. A band at 2572 cm -], assigned to the stretching vibrational mode of an S--H bond, is diminished in the SERS spectra, indicating dissociation of the S--H group in the adsorbed species.…”
Section: Resultsmentioning
confidence: 99%
“…The spectral changes are at- tributed to adsorption modes of the compound at the silver and iron surfaces. Fu~her details and tentative assignments (16,18) of the bands in the Raman and SERS spectra of benzenethiol are tabulated in Table II. A band at 2572 cm -], assigned to the stretching vibrational mode of an S--H bond, is diminished in the SERS spectra, indicating dissociation of the S--H group in the adsorbed species.…”
Section: Resultsmentioning
confidence: 99%
“…In this study, the scaling factors are initially taken from the ratio of observed wavenumbers 19 and calculated wavenumbers of TP, and then fitted by the least-squares procedure to the observed wavenumbers in Ar matrix-isolated IR and Raman of free TP. In this study, the scaling factors are initially taken from the ratio of observed wavenumbers 19 and calculated wavenumbers of TP, and then fitted by the least-squares procedure to the observed wavenumbers in Ar matrix-isolated IR and Raman of free TP.…”
Section: Theoretical Calculationsmentioning
confidence: 99%
“…TP molecule has a planar structure, which is consistent with the previous results. Table 3 presents theoretical scaled wavenumbers (cm 1 ), PEDs, observed wavenumbers 19 and assignments of TP. In this calculation, r cal C-S D 1.788Å, r cal S-H D 1.347Å and < cal CSH D 96.8°.…”
Section: Theoretical Calculationsmentioning
confidence: 99%
“…and Raman spectra of the solids are very similar, indi cating monomeric structures in the solid state also ( Table 2). Spectra have been assigned by compari son with spectra of RHgSPh (R=Ph [5], Me), (PhShHg [5], PhSH and (PhSh [10], PhOH [11], PhzO [12], MeOPh [13], and a range of PhHg" [5,6,14,15] and MeHg" [6,8,16,17] compounds. Methylmercury(II) modes are clearly identified by band intensities which are similar in both MeHgSPh and MeHgOPh.…”
Section: Rhgoph (R = Me Ph)mentioning
confidence: 99%