�ber einige Polygermane

Organogermanium( IV ), Organotin( IV ) and Organolead( IV ) Compounds Containing at Least One M  C σ‐ or π‐Bond and/or M  M Bond Organometallic Hydrides of Germanium( IV ), Tin( IV ) and Lead( IV ) Organometallic Halides of Germanium( IV ), Tin( IV ) and Lead( IV )

show abstract

Investigations on organogermanium compounds. XIII: Synthesis of linear peralkylpolygermanes. Mechanism of the reaction of trialkylgermyl alkali metal compounds with trialkylhalogenogermanes

Bulten¹,

Noltes²

1972

Recl. Trav. Chim. Pays‐Bas

View full text Add to dashboard Cite

A full report is given of our investigations into the synthesis of a series of linear peralkylpolygermanes, both by reacting organohalogenogermanes with alkali metals and by coupling of organohalogenogermanes with trialkylgermyl alkali metalThe latter type of reaction always gives in addition to the asymmetric compound R,GeGeR,', varying amounts of the symmetrical products R6Ge2 and R6'Ge,. Evidence is presented that these side-products are formed by a nucleophilic cleavage of the Ge--Ge bond of the primary asymmetrical coupling products, rather than by a halogen-metal exchange reaction.

show abstract

�ber einige Polygermane

Cited by 5 publications

References 4 publications

By Reaction with Organometallic Reagents

By Reaction with Organometallic Reagents

Synthesis ofM(IV) Organometallic Compounds, whereM = Ge,Sn,Pb

Investigations on organogermanium compounds. XIII: Synthesis of linear peralkylpolygermanes. Mechanism of the reaction of trialkylgermyl alkali metal compounds with trialkylhalogenogermanes

Contact Info

Product

Resources

About