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Gutbier, A.; Flury, Ferdinand

doi:10.1002/zaac.19040380121

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Catalytic Decomposition1

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1939

1965

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“…10) in 1902 (170) showed that hydrazine spontaneously decomposed in contact with active Pt to liberate ammonia, nitrogen, and hydrogen. The equation proposed was Pt 2N2H4 -> 2NHS + N2 + H2 If hydroxyl ion was present, the proportion of hydrogen increased and the ratio of gases obtained approached the equation Pt 3N2H4-» 2NH3 + 2N2 + 3H2 -Two years later Gutbier and Neundlinger (77) showed that in the absence of the hydroxyl ion pure hydrazine in contact with oxygen-free platinum black decomposed to form 3N2H4 ^4NH3 + N2 Neither hydrogen nor nitrous oxide was formed.…”

Section: Catalytic Decompositionmentioning

confidence: 96%

Hydrazine as a Reducing Agent for Organic Compounds (Catalytic Hydrazine Reductions)

Furst¹,

Berlo²,

Hooton³

1965

Chem. Rev.

295

116

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Section: Catalytic Decompositionmentioning

confidence: 96%

Hydrazine as a Reducing Agent for Organic Compounds (Catalytic Hydrazine Reductions)

Furst¹,

Berlo²,

Hooton³

1965

Chem. Rev.

295

116

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“…The aminoguanidinium phosphotungstate (145), tetrabromoaurate (57), hexabromotellurite (56), and tetrachloropalladinate (55) have been described, and in addition a complex compound with thiourea (5) has been prepared. Hantzsch (58) has shown that a primary sulfate of aminoguanidine is formed in absolute sulfuric acid, aminoguanidine in this case acts as a tetraacid base.…”

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confidence: 99%