Beyond 2,5-furandicarboxylic acid: <i>status quo</i>, environmental assessment, and blind spots of furanic monomers for bio-based polymers

Annatelli, Mattia; Sánchez-Velandia, Julián E.; Mazzi, Giovanna; Pandeirada, Simão V.; Giannakoudakis, Dimitrios; Rautiainen, Sari; Esposito, Antonella; Thiyagarajan, Shanmugam; Richel, Aurore; Triantafyllidis, Konstantinos S.; Robert, Tobias; Guigo, Nathanael; Sousa, Andreia F.; García-Verdugo, Eduardo; Aricò, Fabio

doi:10.1039/d4gc00784k

Green Chem.

2024

DOI: 10.1039/d4gc00784k

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Beyond 2,5-furandicarboxylic acid: status quo, environmental assessment, and blind spots of furanic monomers for bio-based polymers

Mattia Annatelli,

Julián E. Sánchez-Velandia,

Giovanna Mazzi

et al.

Abstract: Since 5-(hydroxymethyl)furfural (HMF) has been labelled as the “sleeping giant” of the bio-based platform-chemical realm, numerous investigations have been devoted to the exploitation of this versatile molecule and its endless...

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Cited by 4 publications

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One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS₂‐Decorated Carbonaceous Sugarcane Bagasse

Hao Nguyen,

Dinh Le,

Le Nguyen

et al. 2024

ChemSusChem

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Exploring the transformation of carbohydrates into valuable chemicals offers a promising and eco‐friendly method for utilizing renewable biomass resources. Developing a bi‐functional, sustainable heterogeneous catalyst is of utmost importance to attain a high level of selectivity for the desired product, 2,5‐diformylfuran (DFF), in this direct conversion process. In this study, we developed a highly effective catalytic system to convert diverse carbohydrates into DFF. Our approach involved utilizing a MoS2 catalyst supported by amorphous carbon derived from sulfonated sugarcane biomass. The MoS2@SBG‐SO3H composite was successfully synthesized using a facile and highly efficient method. The transformation of fructose into DFF achieved a significant yield of 70% for 5 h at 160 °C using a one‐step and one‐pot reaction through dehydration and oxidation with oxygen. The oxidation of 5‐hydroxymethylfurfural (HMF) into DFF using MoS2@SBG‐SO3H was obtained at 94% DFF within 5 h; the activation energy was 38.3 kJ.mol‐1. The catalyst displayed convenient recovery and reusability. The direct synthesis of DFF from various carbohydrates, such as sucrose, glucose, maltose, and lactose, resulted in favorable yields. Our research provides a quick, green, and efficient process for preparing carbon‐based solid acid catalysts and DFF.

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One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS₂‐Decorated Carbonaceous Sugarcane Bagasse

Hao Nguyen,

Dinh Le,

Le Nguyen

et al. 2024

ChemSusChem

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Fully biobased poly(butylene furanoate) copolyesters from renewable 2,3-butanediol: Much more than just strengthening and toughening

Tu,

Zhang,

et al. 2024

European Polymer Journal

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Furan-rich, biobased transfection agents as potential oligomeric candidates for intracellular plasmid DNA delivery

Al Hoque,

Kannaboina,

Abraham

et al. 2024

RSC Adv.

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Beyond 2,5-furandicarboxylic acid: status quo, environmental assessment, and blind spots of furanic monomers for bio-based polymers

Abstract: Since 5-(hydroxymethyl)furfural (HMF) has been labelled as the “sleeping giant” of the bio-based platform-chemical realm, numerous investigations have been devoted to the exploitation of this versatile molecule and its endless...

Cited by 4 publications

References 296 publications

One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS₂‐Decorated Carbonaceous Sugarcane Bagasse

One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS₂‐Decorated Carbonaceous Sugarcane Bagasse

Fully biobased poly(butylene furanoate) copolyesters from renewable 2,3-butanediol: Much more than just strengthening and toughening

Furan-rich, biobased transfection agents as potential oligomeric candidates for intracellular plasmid DNA delivery

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Beyond 2,5-furandicarboxylic acid: status quo, environmental assessment, and blind spots of furanic monomers for bio-based polymers

Abstract: Since 5-(hydroxymethyl)furfural (HMF) has been labelled as the “sleeping giant” of the bio-based platform-chemical realm, numerous investigations have been devoted to the exploitation of this versatile molecule and its endless...

Cited by 4 publications

References 296 publications

One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS2‐Decorated Carbonaceous Sugarcane Bagasse

One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS2‐Decorated Carbonaceous Sugarcane Bagasse

Fully biobased poly(butylene furanoate) copolyesters from renewable 2,3-butanediol: Much more than just strengthening and toughening

Furan-rich, biobased transfection agents as potential oligomeric candidates for intracellular plasmid DNA delivery

Contact Info

Product

Resources

About

One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS₂‐Decorated Carbonaceous Sugarcane Bagasse

One‐Pot Effective Approach to 2,5‐Diformylfuran From Carbohydrates Using MoS₂‐Decorated Carbonaceous Sugarcane Bagasse