We present the exact O(α) correction to the process e + e − → ff + γ, f = e, for ISR⊕FSR at and beyond LEP2 energies. We give explicit formulas for the completely differential cross section. As an important application, we compute the size of the respective sub-leading corrections of O(αL) to the ff cross section, where L is the respective big logarithm in the renormalization group sense so that it is identifiable as L = ln |s|/m e 2 when s is the squared e + e − cms energy. Comparisons are made with the available literature. We show explicitly that our results have the correct infrared limit, as a cross-check. Some comments are made about the implementation of our results in the framework of the Monte Carlo event generator KK MC.