“…Reagent grade oxide powders with an appropriate molar ratio of ZnO, and Nb 2 O 5 (99.9% purity each, Alfa Chemicals, USA) were used for preparing Zn 3 4,12 The two series of powders were characterized by light scattering (Mastersizer 2000, Malvern Instruments, UK) for particle size, B.E.T for surface area (Micromeritics, ASAP2000 BET, USA), electronic probe microanalyzer (EPMA, Joel, JXA-8600SX, Japan) equipped with WDS for chemical composition, and X-ray diffractometer (XRD, PW 1830, Philips, The Netherlands) for the crystalline structure.…”