Bicyclo[2.2.1]hept-2-ene (norbornene)

Alberico, Dino; Paquin, Jean‐François

doi:10.1002/047084289x.rn00938

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Intramolecular Couplings1

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2019

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“…Variations on the linkers and substitutions were later investigated by the same group. 94,95 In 2018, Zhou and co-workers utilized the redox-relay Heck reaction as the termination step to access tetrahydronapthalene (76a-c) and indane (76d) scaffolds (Scheme 43). 96,97 Preliminary studies of the asymmetric version was also described using a chiral phosphoramidite as the ligand, though the enantioselectivity and yield were moderate.…”

Section: Intramolecular Couplingsmentioning

confidence: 99%

Palladium/Norbornene Cooperative Catalysis

2019

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Palladium/norbornene cooperative catalysis has emerged as a distinct approach to construct polyfunctionalized arenes from readily available starting materials. This Review provides a comprehensive overview of this field, including the early stoichiometric investigations, catalytic reaction developments, as well as the applications in the syntheses of bioactive compounds and polymers. The section of catalytic reactions is divided into two parts according to the reaction initiation mode: Pd(0)-initiated reactions and Pd(II)-initiated reactions.

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Section: Intramolecular Couplingsmentioning

confidence: 99%