Bimetallic Manganese Cobalt Phosphide Nanodots–Modified Graphitic Carbon Nitride for High‐Performance Hydrogen Production

Wu, Jiacong; Li, Chunmei; Zhang, Wenli; Han, Juan; Wang, Lei; Wang, Shuhao

doi:10.1002/ente.201800927

Cited by 20 publications

(6 citation statements)

References 48 publications

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“…In addition, the multiple absorption peaks from 1214 to 1408 cm À1 belong to C─N stretching vibration mode, and between 1408 and 1635 cm À1 are due to vibration absorption of the repeated triazine structural units, whereas ranging from 3000 to 3450 cm À1 are put down to the stretching vibration of NH groups. [53] Furthermore, umpg-C 3 N 4 exhibits similar FT-IR spectra relative to pure g-C 3 N 4 , which further confirms the fact that the basic structure of pure g-C 3 N 4 has not been damaged after mesoporous formation.…”

Section: Resultssupporting

confidence: 64%

Ultrathin Mesoporous Carbon Nitride Nanosheets Prepared Through a One‐Pot Approach towards Enhanced Photocatalytic Activity

et al. 2020

Energy Tech

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It is still a huge challenge to design a high‐efficiency ultrathin mesoporous nonmetallic photocatalyst by facile eco‐friendly approach for simultaneously enhanced photocatalytic performance for degradation organic pollutant and H2 generation from water splitting. Herein, ultrathin mesoporous carbon nitride nanosheets are prepared via a one‐step thermal polycondensation approach using urea and ammonium carbonate ((NH4)2CO3) as precursor, where the small molecules generated in the thermal treatment process are environmentally friendly. It exhibits high photocatalytic degradation bisphenol A performance and H2 evolution activity compared with the bulk graphitic carbon nitride (g‐C3N4) nanosheet. The improvement of photocatalytic performance results from the ultrathin mesoporous structure with enlarged specific surface area and the abundant mesoporous channels, which facilitates the light absorption and promotes the separation efficiency of photogenerated electron–hole pairs. This work demonstrates a facile eco‐friendly approach to modulate g‐C3N4 morphology for improving its photocatalytic performance.

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Section: Resultssupporting

confidence: 64%

Ultrathin Mesoporous Carbon Nitride Nanosheets Prepared Through a One‐Pot Approach towards Enhanced Photocatalytic Activity

et al. 2020

Energy Tech

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“…This shift was related to the electron loss of t-CN when in contact with CoFeP NCs. [15,39] The Co 2p spectrum of CoFeP displayed two bands at 778.6 eV (2p 3/2 ) and 793.4 eV (2p 1/2 ), associated with a CoP chemical environment (Figure 2d). Two additional bands at 781.6 eV (2p 3/2 ) and 797.5 eV (2p 1/2 ) were assigned to oxidized cobalt species arising from the exposure of the sample to air during handling and transportation.…”

Section: Resultsmentioning

confidence: 99%

Tubular CoFeP@CN as a Mott–Schottky Catalyst with Multiple Adsorption Sites for Robust Lithium−Sulfur Batteries

Zhang

Biendicho

et al. 2021

Advanced Energy Materials

167

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“…NaH 2 PO 2 TPR Nanodots (2020) [167] 34. Mn 0.67 Co [168] 35. FeCoP CoCl 2 , FeCl 3 NaH 2 PO 2 Hydrothermal + annealing method Sea urchin shape (2022) [169] 36.…”

Section: Structural Propertiesmentioning

confidence: 99%

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

Sharma

Choudhary

Kumar

et al. 2023

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Transition metal phosphides (TMP) posses unique physiochemical, geometrical, and electronic properties, which can be exploited for different catalytic applications, such as photocatalysis, electrocatalysis, organic catalysis, etc. Among others, the use of TMP for organic catalysis is less explored and still facing many complex challenges, which necessitate the development of sustainable catalytic reaction protocols demonstrating high selectivity and yield of the desired molecules of high significance. In this regard, the controlled synthesis of TMP‐based catalysts and thorough investigations of underlying reaction mechanisms can provide deeper insights toward practical achievement of desired applications. This review aims at providing a comprehensive analysis on the recent advancements in the synthetic strategies for the tailored and tunable engineering of structural, geometrical, and electronic properties of TMP. In addition, their unprecedented catalytic potential toward different organic transformation reactions is succinctly summarized and critically analyzed. Finally, a rational perspective on future opportunities and challenges in the emerging field of organic catalysis is provided. On the account of the recent achievements accomplished in organic synthesis using TMP, it is highly anticipated that the use of TMP combined with advanced innovative technologies and methodologies can pave the way toward large scale realization of organic catalysis.

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Bimetallic Manganese Cobalt Phosphide Nanodots–Modified Graphitic Carbon Nitride for High‐Performance Hydrogen Production

Cited by 20 publications

References 48 publications

Ultrathin Mesoporous Carbon Nitride Nanosheets Prepared Through a One‐Pot Approach towards Enhanced Photocatalytic Activity

Ultrathin Mesoporous Carbon Nitride Nanosheets Prepared Through a One‐Pot Approach towards Enhanced Photocatalytic Activity

Tubular CoFeP@CN as a Mott–Schottky Catalyst with Multiple Adsorption Sites for Robust Lithium−Sulfur Batteries

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

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