2021
DOI: 10.1002/ange.202113665
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Bimetallic Two‐Dimensional Metal–Organic Frameworks for the Chemiresistive Detection of Carbon Monoxide

Abstract: This paper describes the demonstration of a series of heterobimetallic, isoreticular 2D conductive metal–organic frameworks (MOFs) with metallophthalocyanine (MPc, M=Co and Ni) units interconnected by Cu nodes towards low‐power chemiresistive sensing of ppm levels of carbon monoxide (CO). Devices achieve a sub‐part‐per‐million (ppm) limit of detection (LOD) of 0.53 ppm toward CO at a low driving voltage of 0.1 V. MPc‐based Cu‐linked MOFs can continuously detect CO at 50 ppm, the permissible exposure limit requ… Show more

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Cited by 7 publications
(2 citation statements)
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“…Common examples of recognition elements are metal oxides [11], polymers [12], carbon nanotubes [13], and metalorganic frameworks [14]. The analyte adsorbs onto the recognition element and, through either physical or chemical interactions, alters some property of it (e.g., mass [15], electrical resistance [16], or color [17]). This change in property of the recognition element is converted by a transducer (e.g., a quartz crystal microbalance [18] in the case of a gravimetric sensor) into an electrical signal that is subsequently used to infer the concentration of the analyte in the gas.…”
Section: Introductionmentioning
confidence: 99%
“…Common examples of recognition elements are metal oxides [11], polymers [12], carbon nanotubes [13], and metalorganic frameworks [14]. The analyte adsorbs onto the recognition element and, through either physical or chemical interactions, alters some property of it (e.g., mass [15], electrical resistance [16], or color [17]). This change in property of the recognition element is converted by a transducer (e.g., a quartz crystal microbalance [18] in the case of a gravimetric sensor) into an electrical signal that is subsequently used to infer the concentration of the analyte in the gas.…”
Section: Introductionmentioning
confidence: 99%
“…T he development model of the fossil-energy economy in today's world has led to the uncontrolled emission of large amounts of gaseous pollutants such as nitrides, sulfides, carbides, and volatile organic compounds, resulting in serious environmental pollution problems. 1 Among them, nitrogen dioxide, as a major contributor to photochemical smog and acid rain, poses significant threats to the ecological environment. Moreover, it can lead to respiratory system disorders in humans, such as bronchitis, pulmonary edema, and asthma.…”
mentioning
confidence: 99%