Flexible
piezoelectric energy harvesters (f-PEHs) have recently
become popular alternative power sources for smart and wearable devices.
For applications in self-powered wearable devices and biomedical applications,
f-PEHs should exhibit high flexibility, nontoxicity, and excellent
piezoelectricity. In this study, we developed high-efficiency ultra-f-PEHs
based on electrospun piezoelectric composite fiber (PCF) membranes
composed of lead-free (Ba0.85Ca0.15)(Ti0.90Zr0.10)O3 (BCTZ) nanoparticles (NPs)
and poly(vinylidene fluoride-co-trifluoroethylene)
(P(VDF-TrFE)) fibers. In particular, post-treatments, including post-crystallization
and an extra-poling process, were exploited to further enhance the
piezoelectricity of the PCFs. The PCF membrane reached an output voltage
of 36.5 V, a current signal of 1.09 μA, and an effective output
power of 13.2 μW, which are higher compared to the previously
reported PCF-based energy harvesters. Furthermore, an ultra-f-PEH
consisting of aluminum electrodes, PCF membranes, and polydimethylsiloxane
elastomers was proposed and successfully monitored tiny bio-signals,
such as carotid pulses, vocalization, and articular bending motions.
This study provides suggestions for applications in wearable and biomedical
self-powered electronics using piezoelectric energy-harvesting systems.