Bio‐oil Deoxygenation by Catalytic Pyrolysis: New Catalysts for the Conversion of Biomass into Densified and Deoxygenated Bio‐oil

Abstract

This work proposes an innovative catalytic pyrolysis process that converts bio-refinery residues, such as spent grains, into intermediate bio-oil with improved properties compared to traditional bio-oils, which allows the use of existing crude-oil refinery settings for bio-oil upgrading into fuels. The integration of bio-oil into a crude-oil refinery would decrease the economic disadvantage of biomass compared to fossil fuels. The catalytic pyrolysis was able to produce bio-oil with a lower O and N content and high levels of aliphatics and H by using activated serpentine and olivine at 430-460 °C. The activated materials seem to be beneficial to the bio-oil energy content by increasing it from less than 20 MJ kg(-1) in the original biomass to 26 MJ kg(-1). Approximately 70-74 % of the starting energy remains in the bio-oil using activated olivine (ACOL) and activated serpentine (ACSE) at 430 °C, whereas only 52 % is retained using alumina (ALU) at the same temperature. There was a strong reduction of the O content in the bio-oils, and the deoxygenation power decreased in the following order: ACOL>ACSE>ALU. In particular, ACOL at 430-460 °C was able to reduce the O content of the bio-oil by 40 %. The oxygenated bio-oil macromolecules interact in the catalyst's active sites with the naturally present metallic species and undergo decarboxylation with the formation of C(5)-C(6) O-depleted species.

Hydrodeoxygenation of the aqueous fraction of bio-oil with Ru/C and Pt/C catalysts

“…These factors all limitthe direct usage of pyrolysis oil as a liquid transportation fuel. Several options have been proposed to convert bio-oils using conventional crude-oil technologies such as thermalcatalytic-cracking, hydrotreating, hydrocracking and aqueous phase processing [9][10][11][12][13][14][15].…”

The Efficient and Sustainable Pyrolysis and Gasification of Biomass by Catalytic Processes

“…One of the most effective methods to improve the qualities of bio-oils is to use catalysts in biomass pyrolysis [61][62][63][64]. For instance, Smet et al [65] presented the slow catalytic pyrolysis of rapeseed cake using three different catalysts.…”

Heterogeneous catalysts for advanced bio-fuel production through catalytic biomass pyrolysis vapor upgrading: a review

“…It is worthwhile 103 to mention that Pt and Ru metals exhibit higher hydrogenation activity, although they show 104 lower tolerance of sulfur impurities 36,37 . 105 The high hydrogen consumption in the bio-oil HDO process is the main drawback of this 106 technology. Further, high pressure process which leads to high operational cost could be 107 considered as the other disadvantage.…”