Biobased Green Lubricants: Physicochemical, Tribological and Toxicological Properties of Fatty Acid Ionic Liquids

Fan, Mingjin; Ma, Lin; Zhang, Chaoyang; Wang, Zijing; Ruan, Jiacheng; Han, Min−Koo; Ren, Yue; Zhang, Chi; Yang, Dongxu; Zhou, Feng; Liu, Weimin

doi:10.1080/10402004.2017.1290856

Cited by 37 publications

(14 citation statements)

References 37 publications

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“…Viscosity index can accurately measure the viscosity‐temperature properties of lubricants. As shown in Table , the viscosity and viscosity index of all the [Ch][MA] ILs whether at 40°C or 100°C is increased when the alkyl chain becomes longer . For [Ch][Ethylhex], the viscosity and viscosity index decreased due to the presence of the ethyl side chain .…”

Section: Resultsmentioning

confidence: 96%

“…As shown in Table 2, the viscosity and viscosity index of all the [Ch][MA] ILs whether at 40°C or 100°C is increased when the alkyl chain becomes longer. 12 For [Ch]…”

Section: Viscosity-temperature Propertiesmentioning

confidence: 99%

“…Due to the flexibility in introduction of different cations and anions into ILs, this particular restriction may be overcome by adjusting the structure of the ILs, thus receiving lubricants with both good lubricating properties and green environmental performance. Halogen‐free ILs with better toxicological or biodegradable properties, such as carboxylate ILs, have been already reported . Among others, Vladimir Totolin, Ichiro Minami, Pranesh Aswath, and Jun Qu have worked on halogen‐free ILs as base oils and additives, In this direction, Bharat Bhushan has provided a review on green molecular lubrication.…”

Section: Introductionmentioning

confidence: 99%

“…Halogen-free ILs with better toxicological or biodegradable properties, such as carboxylate ILs, have been already reported. 12,13 Among others, Vladimir Totolin, 14,15 Ichiro Minami, 16 Pranesh Aswath, 17 and Jun Qu 18,19 have worked on halogen-free ILs as base oils and additives, In this direction, Bharat Bhushan 20 has provided a review on green molecular lubrication.…”

Section: Introductionmentioning

confidence: 99%

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The ecotoxicity and tribological properties of choline monocarboxylate ionic liquid lubricants

Fan

Zhang

et al. 2019

Lubrication Science

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In this work, a series choline monocarboxylate ionic liquids ([Ch][MA] ILs) were synthesized. The physicochemical properties and lubricating efficiency of the ILs on copper and aluminum discs were systematically investigated. At the same time, their ecotoxicity was explored on aquatic organisms. In comparison with 1‐butyl‐3‐methyl imidazolium tetrafluoroborate (L‐B104), which is a kind of traditional IL, [Ch][MA] ILs exhibited excellent lubricating properties and low toxicities, thus can be considered as environmentally friendly lubricants in tribology.

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Section: Resultsmentioning

confidence: 96%

“…As shown in Table 2, the viscosity and viscosity index of all the [Ch][MA] ILs whether at 40°C or 100°C is increased when the alkyl chain becomes longer. 12 For [Ch]…”

Section: Viscosity-temperature Propertiesmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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The ecotoxicity and tribological properties of choline monocarboxylate ionic liquid lubricants

Fan

Zhang

et al. 2019

Lubrication Science

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“…To obtain low toxicity, good stability, and biological activity, anions derived from naturally occurring substances are suitable as counterions to prepare ILs . Some examples of natural bio‐based anions in the third‐generation ILs include lactic acid, nicotinic acid, oleic acid, pelargonic acid, acetic acid, salicylic acid, amino acid, and fatty acid . In a recent study, the third‐generation protic ILs were synthesized using an herbicide, thifensulfuronmethyl (TFM).…”

Section: Toxicity Of Ionic Liquids Toward Microorganismsmentioning

confidence: 99%

An Overview on the Toxicological Properties of Ionic Liquids toward Microorganisms

Sivapragasam

Moniruzzaman

Goto

2020

Biotechnology Journal

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Ionic liquids (ILs), a class of materials with unique physicochemical properties, have been used extensively in the fields of chemical engineering, biotechnology, material sciences, pharmaceutics, and many others. Because ILs are very polar by nature, they can migrate into the environment with the possibility of inclusion in the food chain and bioaccumulation in living organisms. However, the chemical natures of ILs are not quintessentially biocompatible. Therefore, the practical uses of ILs must be preceded by suitable toxicological assessments. Among different methods, the use of microorganisms to evaluate IL toxicity provides many advantages including short generation time, rapid growth, and environmental and industrial relevance. This article reviews the recent research progress on the toxicological properties of ILs toward microorganisms and highlights the computational prediction of various toxicity models.

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Impacts of synthesis variables on spectroscopics evaluation of biobased fatty amide as alkylammonium salt’s precursor for perovskite

Mustafa,

Jumaah,

Yoshizawa-Fujita

et al. 2024

Construction and Building Materials

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Biobased Green Lubricants: Physicochemical, Tribological and Toxicological Properties of Fatty Acid Ionic Liquids

Cited by 37 publications

References 37 publications

The ecotoxicity and tribological properties of choline monocarboxylate ionic liquid lubricants

The ecotoxicity and tribological properties of choline monocarboxylate ionic liquid lubricants

An Overview on the Toxicological Properties of Ionic Liquids toward Microorganisms

Impacts of synthesis variables on spectroscopics evaluation of biobased fatty amide as alkylammonium salt’s precursor for perovskite

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