Evaporators used in power plants for sugar production are vessels with two boxes of heat exchangers. These heat exchangers made of a low-corrosion resistance material are frequently replaced during the alcohol production process. In view of the growing production of cane, sugar, and alcohol, and the corrosion of materials used in power plants, it was necessary to find alternative materials for carbon steel applied in the evaporators. A comparative study of the corrosion resistance of stainless steel as well as unalloyed and alloyed carbon-manganese steels in neutral and acid sugar cane juice electrolytes is presented. The alloyed carbon steels showed the best corrosion behavior in an acid environment compared to a neutral medium. Among the alloyed carbon steels, ASTM T11 and ASTM T22 steels provided the highest corrosion resistance in sugar cane juice.
IntroductionThe Brazilian sugar and alcohol industry experienced two great developments in the last decades. The first occurred from 1975 to 1985, associated with the increase in ethanol production, while the second one is related with the increase in sugar production and export since 1995 until today. The evaporators applied in power plants for sugar production are vessels with two boxes of heat exchangers whose function is to evaporate water in the sugar cane juice, which contains 85 % of water. The water content is reduced to 40 % using multiple-effect evaporators.Sugar cane contains water (65-75 wt-%), solids (11-18 wt-%), fibers (8-14 wt-%), organic and inorganic acids, proteins, starch, wax, and dyes [1]. The solids include saccharose, glucose, fructose, and salts. The vapor comprises natural organic acids from sugar cane and other acids produced in the process. The condensed water contains dissolved gases, aldehydes, alcohols, organic acids, and nitrogen compounds. Sugar cane juice is acidic with a pH value of 5.6 at extraction. This acidic property is accounted for by the presence of a variety of acids, namely aconitic, citric, malic, oxalic, glycolic, mesaonic, tartic, succinic, fumaric, and syringic acid in sugar cane juice [1]. In addition to these acids, there are approximately 50 different kinds of microorganisms present in the green cane which are very active. These microorganisms will contribute to a rather quick drop in pH (3.1) of the sugar cane juice once extracted [1]. Moreover, several minerals like water, salt, sulfate, and silica are also present throughout the process and promote surface degradation of equipments in the alcohol industry by a wear mechanism.The steel tubes of evaporators are frequently substituted due to corrosion. The corrosion process increases with higher temperature and acidity. Several researchers studied the corrosion performance of steels in acid and neutral organic media [2][3][4][5][6][7][8][9][10][11]. The inhibitive capabilities of some organic compounds on the electrochemical corrosion of mild and stainless steels in acid and alkaline media were reported [2][3][4][5][6][7][8][9][10][11]. Adsorption of organic comp...