The complex research of influence of a structural condition of metal on resistance to corrosion destruction of the low-alloyed steel, operated in biocorrosion environments, is conducted. It is established that the ferritic component of a structure resists better in the environment modeling conditions of impact of biogenous gases on metal under the exfoliated anticorrosive covering. Ferrite – carbide mix, in the form of beynit, has a bigger resistance in the environment reproducing conditions of lack of biogenous factors. Existence in beynitny structure of a martensitic component leads to the largest resistance of biocorrosion in the environment modeling conditions of anaerobic corrosion with biogenous gases.