Biodegradable UV-Blocking Films through Core–Shell Lignin–Melanin Nanoparticles in Poly(butylene adipate-co-terephthalate)

Abstract

Biodegradable and renewable UV-shielding films are highly demanded to meet the increasing sustainable requirement for the environment. Lignin as a natural broad UV blocker has gained considerable attention; however, the poor dispersibility within synthetic polymers limited its applications. Thus, a bioinspired melanin-like polydopamine thin layer was incorporated for the first time with lignin nanoparticle (LNP) in this effort, forming a UV-blocking core–shell lignin–melanin nanoparticle (LMNP) with higher compatibility and durability. Subsequently, LNP, LMNP, melanin nanoparticles (MNP), and a mix of LNP and MNP (MixNP) were compounded with poly­(butylene adipate-co-terephthalate) (PBAT), to enhance the UV-barrier capability and photostability of PBAT films. The incorporated LMNPs were well distributed into PBAT, leading to improved tensile properties and thermal stability of the resulting films. All these films possessed remarkable UV-blocking capacity at NP concentration ranging from 0.5 to 5 wt %, blocking almost all of UV-A and more than 80% of UV-B light, while an appreciable optical transmittance could also be achieved. The PBAT–LMNP films displayed a high UV-shielding stability and the best retention in mechanical properties after UV exposure for 40 h. This work provides a very promising approach for fabricating biodegradable PBAT-based UV-blocking films for potential applications in agricultural or food packaging materials where the UV resistance is highly required.

Degradation and Recycling of Films Based on Biodegradable Polymers: A Short Review

“…Poly-butylene adipate-co-terephthalate (PBAT) belongs to biodegradable aliphatic-aromatic polyesters and, thanks to its high ductility, it finds applications in agricultural or food packaging materials and was recently considered as one of the candidate materials for blending with PLA [26,27].…”

Curcumin Incorporated Poly(Butylene Adipate-co-Terephthalate) Film with Improved Water Vapor Barrier and Antioxidant Properties

“…A variety of functional or reinforcing fillers such as SiO 2 , graphene oxide, MgO, AgNP, ZnONP, clay, curcumin, grape seed extract, etc. have been utilized enhance the physical and functional properties of PBAT films [ 9 , 15 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 ]. In this sense, the use of natural bioactive compounds to improve PBAT film properties is an attractive field of research.…”

Enhanced Photodegradation Stability in Poly(butylene adipate-co-terephthalate) Composites Using Organically Modified Layered Zinc Phenylphosphonate

“…Figure 5 shows the UV-Vis transmittance spectra of the PBAT and the PBAT/m-PPZn composite materials between 250–400 cm −1 . The UV-Vis results of the PBAT material show excellent UV-A penetration characteristics; however, they show poor UV-B and UV-C penetration characteristics due to the presence of the benzene ring and carbonyl group [ 36 , 37 ]. The UV-Vis results of the PBAT/m-PPZn composites show better UV barrier properties than that of the PBAT.…”