Biodiesel production from waste cooking oil using a novel biocatalyst of lipase enzyme immobilized magnetic nanocomposite

Parandi, Ehsan; Safaripour, Maryam; Abdellattif, Magda H.; Saidi, Majid; Bozorgian, Alireza; Nodeh, Hamid Rashidi; Rezania, Shahabaldin

doi:10.1016/j.fuel.2021.123057

Cited by 91 publications

(27 citation statements)

References 65 publications

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“… No. Type of feedstock Type of nanomaterials Experimental conditions Biodiesel Yield (%) References 1 Wild mustard seed oil Lanthanum titanium dioxide (LaTiO 3 ) nanoparticles MeOH/oil ratio (4:1), catalyst (100 mg), reaction time (60 min), 80 °C 92.21 [ 132 ] 2 Canola oil αFe 2 O 3 1-x/ZnO x nanoparticles MeOH/oil ratio (11.25:1), ultrasonic power of 278.46 W, irradiation power time 29.22 min, catalyst (47.24%), 65 °C 94.21 [ 133 ] 3 Waste cooking oil (WCO) TiO 2 nano-catalyst MeOH/oil ratio (10:1), 0.01% TiO 2 nano-catalyst coupled with 0.3% NaOH, reaction time (60 min), 60 °C 95 [ 134 ] 4 Mango seed ( Mangifera indica ) extracts ZnO nanocatalyst MeOH/oil ratio (7:2), 10 mL of ZnO nano catalyst, reaction time (60 min), 50 °C 85 [ 135 ] 5 Waste cooking oil (WCO) Candida antarctica Lipase B immobilized on a magnetic hybrid sol-gel nanocomposite MeOH/oil ratio (4:1), catalyst (1 g), reaction time (30 h), 40 °C 96 [ 136 ] 6 Citrus medica seed oil Green CuO nanoparticles MeOH/oil ratio (8:1), catalyst 0.18%, reaction time (120 min), 85 °C 93 [ 137 ] 7 Canola oil ZnO nanocatalyst …”

Section: Nanomaterials In Transesterificationmentioning

confidence: 99%

Recent advances and challenges in the utilization of nanomaterials in transesterification for biodiesel production

Pandit¹,

Banerjee²,

Pandit³

et al. 2023

Heliyon

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Section: Nanomaterials In Transesterificationmentioning

confidence: 99%

Recent advances and challenges in the utilization of nanomaterials in transesterification for biodiesel production

Pandit¹,

Banerjee²,

Pandit³

et al. 2023

Heliyon

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“…32,33 Moreover, organosilane reagents such as 3-aminopropyltrietoxysilane, as well as bifunctional chemical such as glutaraldehyde, are typically linked to the coating to strengthen the enzyme-support bond, particularly when covalent bonding is desired. 34,35 The aforementioned techniques frequently have associated higher production costs since more steps and chemicals are required. Because of this, a few recent studies have emphasized the significance of researching protein−NP interactions by straightforward surface adsorption (by single step); therefore, it is a field of knowledge that needs to be explored.…”

Section: Introductionmentioning

confidence: 99%

Interfacial Hyperactivation of Candida rugosa Lipase onto Ca₂Fe₂O₅ Nanoparticles: pH and Ionic Strength Fine-Tuning to Modulate Protein-Support Interactions

Morales,

Hero,

Ledesma

et al. 2023

Langmuir

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The current study provides a comprehensive look of the adsorption process of Candida rugosa lipase (CRL) on Ca2Fe2O5 iron oxide nanoparticles (NPs). Protein-support interactions were identified across a broad range of pH and ionic strengths (mM) through a response surface methodology, surface charge determination, and spectroscopic and in silico analyses. The maximum quantity of immobilized protein was achieved at an ionic strength of 50 mM and pH 4. However, this condition did not allow for the greatest hydrolytic activity to be obtained. Indeed, it was recorded at acidic pH, but at 150 mM, where evaluation of the recovered activity revealed hyperactivation of the enzyme. These findings were supported by adsorption isotherms performed under different conditions. Based on zeta potential measurements, electrostatic interactions contributed differently to protein-support binding under the conditions tested, showing a strong correlation with experimentally determined immobilization parameters. Raman spectra revealed an increase in hydrophobicity around tryptophan residues, whereas the enzyme immobilization significantly reduced the phenylalanine signal in CRL. This suggests that this residue was involved in the interaction with Ca2Fe2O2 and molecular docking analysis confirmed these findings. Fluorescence spectroscopy showed distinct behaviors in the CRL emission patterns with the addition of Ca2Fe2O5 at pH 4 and 7. The calculated thermodynamic parameters indicated that the contact would be mediated by hydrophobic interactions at both pHs, as well as by ionic ones at pH 4. In this approach, this work adds to our understanding of the design of biocatalysts immobilized in iron oxide NPs.

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“…The content contained in the palm oil waste in the fermentation process obtained nitrogen levels with 7% bentonite nitrogen at 167 ppm, phosphorus levels in bentonite 3% with phosphorus at 20.1 ppm, and the highest K element was obtained in the provision of 3% bentonite at 742 ppm. Biodiesel production is obtained from used oil using the lipase enzyme biocatalyst method with a 96% yield achieved [9].…”

Section: Introductionmentioning

confidence: 99%

Biodiesel Production from POME (Palm Oil Mill Effluent) and Effects on Diesel Engine Perfor-mance

Suardi

Purwanto²,

Kyaw³

et al. 2022

IJMEIR

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one way to reduce the scarcity of fuel oil is to make environmentally friendly alternative fuels such as biodiesel. The utilization of biodiesel can be a new energy source and also help reduce the excessive use of fuel, especially diesel and diesel oil in Indonesia. In Indonesia, the amount of palm oil will reach 49.7 tons by 2021, and this data is up 2.9% from the previous year. Palm fruit is processed into CPO. More palm oil processing will produce waste called POME (Palm Oil Mill Effluent). The diesel engine transesterification method is suitable for the manufacture of biodiesel. The amount of base on the catalyst's surface affects the catalyst's activity. So that the higher the base value on the catalyst, the higher the yield of biodiesel that will be produced. The biodiesel produced will be tested on a 4-stroke diesel engine with a B5 and B10 blending composition. The study's results showed that the density and viscosity values for B5 were 5.8 cSt and 810 Kg/m3 and for B10 were 6.3 cSt and 860 Kg/m3. As for engine performance, power, torque, and SFC for B5 fuel at 4000-watt load conditions and 1000 Rpm, engine speeds are 1.18 Kw, 11.28 Nm, and 256.8 gr/Kw. B10 at 4000-watt load condition and 1000 Rpm engine speed is 1.16 Kw, 11.12 Nm, and 269.2 gr/Kw.

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Biodiesel production from waste cooking oil using a novel biocatalyst of lipase enzyme immobilized magnetic nanocomposite

Cited by 91 publications

References 65 publications

Recent advances and challenges in the utilization of nanomaterials in transesterification for biodiesel production

Recent advances and challenges in the utilization of nanomaterials in transesterification for biodiesel production

Interfacial Hyperactivation of Candida rugosa Lipase onto Ca₂Fe₂O₅ Nanoparticles: pH and Ionic Strength Fine-Tuning to Modulate Protein-Support Interactions

Biodiesel Production from POME (Palm Oil Mill Effluent) and Effects on Diesel Engine Perfor-mance

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Biodiesel production from waste cooking oil using a novel biocatalyst of lipase enzyme immobilized magnetic nanocomposite

Cited by 91 publications

References 65 publications

Recent advances and challenges in the utilization of nanomaterials in transesterification for biodiesel production

Recent advances and challenges in the utilization of nanomaterials in transesterification for biodiesel production

Interfacial Hyperactivation of Candida rugosa Lipase onto Ca2Fe2O5 Nanoparticles: pH and Ionic Strength Fine-Tuning to Modulate Protein-Support Interactions

Biodiesel Production from POME (Palm Oil Mill Effluent) and Effects on Diesel Engine Perfor-mance

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Product

Resources

About

Interfacial Hyperactivation of Candida rugosa Lipase onto Ca₂Fe₂O₅ Nanoparticles: pH and Ionic Strength Fine-Tuning to Modulate Protein-Support Interactions