“…Typical H 2 yield range from 1 to 2 mol of H 2 /mol of glucose, and results in 80-90% of the initial chemical oxygen demand (COD) remaining in the wastewater in the form of various volatile organic acids (VFAs) and solvents, such as acetic, propionic, butyric acids and ethanol [1]. Even under optimal conditions about 60-70% of the original organic matter remains in solution [12][13][14][15]. In spite of theoretical conversion efficiency of 33%, only 15% of the energy from the organic source is typically obtained in the form of H 2 [1,11,38,39].…”