This review delves into the cutting-edge field of bioinspired polymer composites, tackling the complex task of emulating nature’s efficiency in synthetic materials. The research is dedicated to creating materials that not only mirror the strength and resilience found in natural structures, such as spider silk and bone, but also prioritize environmental sustainability. The study explores several critical aspects, including the design of lightweight composites, the development of reversible adhesion methods that draw inspiration from nature, and the creation of high-performance sensing and actuation devices. Moreover, it addresses the push toward more eco-friendly material practices, such as ice mitigation techniques and sustainable surface engineering. The exploration of effective energy storage solutions and the progress in biomaterials for biomedical use points to a multidisciplinary approach to surpass the existing barriers in material science. This paper highlights the promise held by bioinspired polymer composites to fulfill the sophisticated needs of contemporary applications, highlighting the urgent call for innovative and sustainable advancements.