“…In the academic and industrial fields, extensive attention has been attracted to the development of diverse solid sorbents towards efficient CO 2 capture, [4] including but not limited to porous organic polymers (POPs), [5] metal‐organic frameworks (MOFs), [6] carbon‐related materials, [7] modified silica, [8] zeolites, [9] and metal oxides [10] . Among those categories, carbon materials, such as activated carbon, mesoporous carbon, carbon nanofiber, and carbon nanotubes, which could be derived from different carbon precursors (e. g., biomass, biochar, polymer, ionic liquids, and MOFs) and synthesized via various thermal treatment procedures, have been widely deployed in post‐combustion CO 2 capture [11–17] . In order to improve the CO 2 capture capacity of the carbon materials, extensive studies have been conducted via strategies such as heteroatoms‐doping (e. g., O, N, F, or S), [18] inorganic base activation (e. g., NaOH, KOH, NaNH 2 ), [19] utilization of templates during the preparation process, [20–21] and anchoring CO 2 ‐philic functionalities on the surface, [17] aiming at increasing the surface areas, tuning the porosity distributions, and enhancing the interaction strength with CO 2 .…”