Biomass-derived 5-hydroxymethylfurfural (HMF) and 2,5-dimethylfuran (DMF) synthesis as promising alternative fuel: A prospective review

Mehta, Jigesh; Metre, Anand; Bhakhar, Mathurkumar S.; Panwar, D.S.; Dharaskar, Swapnil

doi:10.1016/j.matpr.2021.12.376

Cited by 11 publications

(9 citation statements)

References 65 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Several advantages from experimental deigns were displayed, for instance, (I) it could decrease some error in determining the influence of each determinant and their interactions, (II) the production cost of 5-EMF could be significantly reduced since lower number of batch experiments were carried out, and (III) optimal conditions and maximal yield could be obtained. 27 The effects of independent input parameters such as X 1 (the amount of ChCl added (g)), X 2 (the amount of S-MAC added (g)), X 3 (the reaction temperature (°C)), and X 4 (the reaction time (min) on response of 5-EMF yield) were investigated to find the significant levels using 2 k factorial design at the 95% confidence level. The ranges of factorial design consisting of 16 experiments with their low (−1) and high (1) levels are shown in Table 1.…”

Section: ■ Experimental Sectionmentioning

confidence: 99%

“…They also discussed that Fe 3 O 4 @C–SO 3 H not only gave a yield of 5-EMF (34%) from sucrose conversion at 140 °C for 24 h but also presented good recyclability of catalyst up to six cycles. To date, the new challenge of this research field is technological application for faster/cleaner production of high-value chemicals. , …”

Section: Introductionmentioning

confidence: 99%

“…To date, the new challenge of this research field is technological application for faster/cleaner production of high-value chemicals. 26,27 In this novel work, we studied and developed the green technology for 5-EMF production at short ethanolysis times and low ethanolysis temperatures. Here, 5-EMF was easily produced from the fast ethanolysis of RS under a reusable process over sulfonic-magnetic activated carbon (S-MAC).…”

Section: ■ Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Rapid Formation and Facile Separation of Biofuel 5-EMF over Integration of Sustainable Catalyst with Oxygen Environment under an Ultrasonic-Assisted Ethanolysis System

Maneechakr,

Kurnia,

Bayu

et al. 2023

ACS Sustainable Chem. Eng.

View full text Add to dashboard Cite

In this work, ultrasonic-assisted ethanolysis of raw sugar (RS) into 5-ethoxymethylfurfural (5-EMF) product was performed under a biphasic system under mild conditions. The sulfonic-magnetic activated carbon (S-MAC) was prepared via pyrolysis and sulfonation processes and further applied for catalytic production of 5-EMF. The catalytic behaviors for facile formation/rapid production of 5-EMF were described through several factors such as type of catalyst, S-MAC and choline chloride (ChCl) adding amounts, reaction temperature, reaction time, and ultrasonic power generation. The integrating roles of various catalysts with the introduction of oxygen were described using turnover rate investigation, and the result found to be a great effect for improving the 5-EMF yield via major reactions such as hydrolysis, isomerization, dehydration, and etherification while side reactions for formation of polymeric intermediates were remarkably suppressed. Herein, a maximum yield of 5-EMF (actual yield = 93.2 ± 0.6%) was obtained at a low temperature of 80 °C and short reaction time for 11 min under an optimization process via linear-quadratic designs. Finally, the reusable systems under O2 and N2 addition were compared up to 10 cycles, and the result found that very few changing in 5-EMF yield could be obtained while hard carbon/humins deposited on S-MAC structure was significantly obstructed and reduced in each cycle via special oxidative degradation. In addition, lower energy consumption was required for regeneration of spent catalyst derived from reaction under an oxygen environment. This work was notably expected for further application in practical procedure under a reusable system.

show abstract

Section: ■ Experimental Sectionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: ■ Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Rapid Formation and Facile Separation of Biofuel 5-EMF over Integration of Sustainable Catalyst with Oxygen Environment under an Ultrasonic-Assisted Ethanolysis System

Maneechakr,

Kurnia,

Bayu

et al. 2023

ACS Sustainable Chem. Eng.

View full text Add to dashboard Cite

show abstract

“…Here, a deep eutectic solvent (DES) was also applied for a new generation of recycling process based on remarkable properties such as low vapor pressure/melting points, high thermal stability, good biodegradability and environmental friendliness. 23 The DES integration in the presence of ChCl + MeCN + S@Fe-Cu-C was newly developed and systematically studied for facile/fast/selective production of 5-HMF from CS conversion. The S@Fe-Cu-C was specifically characterized using BET, XRD, SEM-EDS, VSM, XPS, TGA, NH 3 -TPD and Py-FTIR techniques.…”

Section: Introductionmentioning

confidence: 99%

Selective regression models for the rapid upgrading of raw sugar into 5-HMF bio-fuel additive under a sustainable/reusable system

Maneechakr,

Kurnia,

Bayu

et al. 2023

Sustainable Energy Fuels

View full text Add to dashboard Cite

show abstract

“…The environmental and social problems caused by the dependence of the global energy matrix and the chemical synthesis on fossil fuels (oil, coal, and natural gas) motivated the search for sustainable energy sources, with an emphasis on biomass [1][2][3]. Regarding biomass-derived inputs, special attention is directed to carbohydrates, such as fructose, since the conversion of these molecules provides the formation of a spectrum of valuable chemicals [4], including 5-hydroxymethylfurfural [5] and lactic acid [6].…”

Section: Introductionmentioning

confidence: 99%

Investigation of CeO2, MoO3, and Ce2(MoO4)3, Synthesized by the Pechini Method, as Catalysts for Fructose Conversion

et al. 2022

View full text Add to dashboard Cite

Cerium oxide (Ce100), molybdenum oxide (Mo100), and a material containing Ce and Mo (CeMo) were synthesized by the Pechini method, using glycerol as a polyol. These materials were applied for fructose conversion in an aqueous medium. The characterization results show the formation of cerium molybdate (Ce2(MoO4)3) for CeMo. Ce100 presented good thermal stability, and Mo100 sublimation of MoO3 and polymolybdates was verified. CeMo exhibited a mass loss of 19%, associated with the sublimation of MoO3 and polymolybdate species. Additionally, the existence of Bronsted and Lewis acid sites was confirmed, and the addition of Mo to Ce was an efficient strategy to increase the acidity. Regarding the catalytic activity (150 °C and 0.5 to 6 h), Ce100 exhibited low conversions and high selectivity to 5-hydroxymethylfurfural (5-HMF). For Mo100, high conversions, with a significant formation of insoluble materials, were detected. For CeMo, beyond the high activity, a lower formation of insoluble materials was noted. In this case, selectivity toward products from the retro–aldolic route and 5-HMF were obtained. These results indicate that the main factor influencing fructose conversion is an adequate combination of the acid sites. Recycling experiments were carried out, and stability was observed for four cycles, confirming the robustness of this system.

show abstract

Biomass-derived 5-hydroxymethylfurfural (HMF) and 2,5-dimethylfuran (DMF) synthesis as promising alternative fuel: A prospective review

Cited by 11 publications

References 65 publications

Rapid Formation and Facile Separation of Biofuel 5-EMF over Integration of Sustainable Catalyst with Oxygen Environment under an Ultrasonic-Assisted Ethanolysis System

Rapid Formation and Facile Separation of Biofuel 5-EMF over Integration of Sustainable Catalyst with Oxygen Environment under an Ultrasonic-Assisted Ethanolysis System

Selective regression models for the rapid upgrading of raw sugar into 5-HMF bio-fuel additive under a sustainable/reusable system

Investigation of CeO2, MoO3, and Ce2(MoO4)3, Synthesized by the Pechini Method, as Catalysts for Fructose Conversion

Contact Info

Product

Resources

About