Biomass Derived Self‐Doped Carbon Nanosheets Enable Robust Hole Transport Layers with Ion Buffer for Perovskite Solar Cells

Abstract

The diffusion of iodine species and lead leakage during device degradation represent the main obstacles restricting the commercial application of perovskite solar cells (PSCs). Cobalt loaded ultrathin carbon nanosheets (Co(III)‐CNS) derived from biomass are prepared as ion buffer material to construct robust hole transport layers (HTLs). The carbon nanosheets containing trivalent cobalt ions can facilitate the oxidation of the hole transport material while preserving the structural integrity and electrical properties of HTLs under thermal stress, thereby ensuring efficient carrier transport. The two‐dimensional ultrathin graphitized lamellar structure of Co(III)‐CNS is conducive to alleviate the corrosive effects of the outward diffusion of iodine species on HTLs and silver electrodes, while avoiding irreversible degradation of PSCs. With the improvement of HTL composition and the related interfaces, Co(III)‐CNS doped devices can maintain intact device structure under thermal stress and remain above 80 % of the original power conversion efficiency (PCE) after thermal aging at 85 °C for 720 h. Notably, the chemical interactions between heteroatoms of self‐doped carbon nanosheets and the mobile lead ions can effectively alleviate lead leakage and avoid the potential impacts of device degradation on ecosystem. Ultimately, the Co(III)‐CNS doped PSCs with enhanced thermal stability exhibit a champion PCE of 22.32 %.