Biomass-MOF composites in wastewater treatment, air purification, and electromagnetic radiation adsorption – A review

Jiang, Jinxuan; Shi, Yang; Wu, Mingjun; Rezakazemi, Mashallah; Aminabhavi, Tejraj M.; Huang, Runzhou; Jia, Chong; Ge, Shengbo

doi:10.1016/j.cej.2024.152932

Chemical Engineering Journal

2024

DOI: 10.1016/j.cej.2024.152932

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Biomass-MOF composites in wastewater treatment, air purification, and electromagnetic radiation adsorption – A review

Jinxuan Jiang,

Yang Shi,

Mingjun Wu

et al.

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Cited by 18 publications

References 191 publications

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Iron‐MOFs for Biomedical Applications

Yu,

Lepoitevin,

Serre

2024

Adv Healthcare Materials

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Over the past two decades, iron‐based metal–organic frameworks (Fe‐MOFs) have attracted significant research interest in biomedicine due to their low toxicity, tunable degradability, substantial drug loading capacity, versatile structures, and multimodal functionalities. Despite their great potential, the transition of Fe‐MOFs–based composites from laboratory research to clinical products remains challenging. This review evaluates the key properties that distinguish Fe‐MOFs from other MOFs and highlights recent advances in synthesis routes, surface engineering, and shaping technologies. In particular, it focuses on their applications in biosensing, antimicrobial, and anticancer therapies. In addition, the review emphasizes the need to develop scalable, environmentally friendly, and cost‐effective production methods for additional Fe‐MOFs to meet the specific requirements of various biomedical applications. Despite the ability of Fe‐MOFs–based composites to combine therapies, significant hurdles still remain, including the need for a deeper understanding of their therapeutic mechanisms and potential risks of resistance and overdose. Systematically addressing these challenges could significantly enhance the prospects of Fe‐MOFs in biomedicine and potentially facilitate their integration into mainstream clinical practice.

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Iron‐MOFs for Biomedical Applications

Yu,

Lepoitevin,

Serre

2024

Adv Healthcare Materials

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Enhanced Urea Oxidation Reaction Through Layered Double Hydroxides: Insights From ZIF‐67‐Derived Nanostructures

Jeon,

Medvedev,

Seong

et al. 2024

EcoMat

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Layered double hydroxides (LDHs) are ionic layered compounds characterized by anion‐containing intermediate regions within positively charged brucite‐like layers. LDHs have shown high electrochemical activity in energy conversion systems such as batteries and fuel cells. In this study, we developed a hierarchically porous nanostructure derived from zeolitic imidazolate framework‐67, which was subsequently transformed into an LDH structure with varying Ni concentrations. We precisely controlled the Ni‐to‐Co ratio within the LDH structure and investigated how different mole fractions of Co and Ni influence catalytic activity and selectivity for the electrochemical urea oxidation reaction (UOR). LDH structures with low Ni content (up to 40%) demonstrated high activity and selectivity for O2 due to their structural instability and the predominant oxygen evolution reaction (OER) originating from ZIF‐67. In contrast, LDHs with high Ni content (over 60%) supressed OER and exhibited enhanced activity for UOR. The resulting hollow structure with an expanded electrochemically active surface in LDHs with high Ni content could improve mass transport and diffusion at the electrode interface, leading to better reaction kinetics and higher current densities. These findings provide a foundational design guideline for metal–organic framework‐derived nanostructure in UOR. image

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Dynamic construction of a composite solid electrolyte interphase for dendrite-free lithium metal batteries via lithium-antimony self-alloying

Min,

Park,

Choi

et al. 2024

Adv Compos Hybrid Mater

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Biomass-MOF composites in wastewater treatment, air purification, and electromagnetic radiation adsorption – A review

Cited by 18 publications

References 191 publications

Iron‐MOFs for Biomedical Applications

Iron‐MOFs for Biomedical Applications

Enhanced Urea Oxidation Reaction Through Layered Double Hydroxides: Insights From ZIF‐67‐Derived Nanostructures

Dynamic construction of a composite solid electrolyte interphase for dendrite-free lithium metal batteries via lithium-antimony self-alloying

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