This work is part of a study of different types of plant-based biomass to elucidate their capacity for valorisation via a managed carbonation step involving gaseous carbon dioxide (co 2). the perspectives for broader biomass waste valorisation was reviewed, followed by a proposed closed-loop process for the valorisation of wood in earlier works. the present work newly focusses on combining agricultural biomass with mineralised co 2. Here, the reactivity of selected agricultural biomass ashes with co 2 and their ability to be bound by mineralised carbonate in a hardened product is examined. three categories of agricultural biomass residues, including shell, fibre and soft peel, were incinerated at 900 ± 25 °C. The biomass ashes were moistened (10% w/w) and moulded into cylindrical samples and exposed to 100% CO 2 gas at 50% RH for 24 h, during which they cemented into hardened monolithic products. the calcia in ashes formed a negative relationship with ash yield and the microstructure of the carbonate-cementing phase was distinct and related to the particular biomass feedstock. this work shows that in common with woody biomass residues, carbonated agricultural biomass ash-based monoliths have potential as novel low-carbon construction products. This paper discusses environmental issues that are of relevance to the sustainable use of resources and protection of the environment. By re-using abundantly available agricultural biomass residues, and by reducing the amount of cement used in construction and their associated carbon emissions, significant potential sustainability gains can be realised. In consideration of this, a low carbon management option for biomass residues is proposed. Agricultural activities generate huge volumes of biomass residues, with crop derived waste accounting for 94% of global biomass production 1. These include cereals (wheat, rice, maize, and barley), sugarcane, soybean, and some oil crops, fruits, vegetables, roots and tubers, and sugar beet 1. These residues are expected to increase as the world's population exceeds 11 Billion by 2,100 2. It is estimated that globally 140 Gt of agricultural residues are generated each year 3,4. According to Lal (2019) 5 , the total annual amount of crop residue produced globally is estimated at 2.8 Gt for cereal crops, 3.1 Gt for 17 major cereals and legumes, and 3.8 Gt for 27 common food crops. The IEA CCC (2015) 6 reports the global resource for unexploited cereal crop residues amounts to 517 Mt. The FAO (2002) 7 projects that from 1999 to 2030, the agricultural sector of developing countries will increase by 13% or 120 M ha. Predictions for global cereal yield suggest an increase in the range 0.9% per annum over the period 2005/2007-2050, continuing a trend of long-term declining yield growth (20 y average yield increase declined from ~ 3% pa in 1982, to ~ 1% by 2005) 8,9. The intensification of agricultural and increased crop yield (producing more per unit of land) will undoubtedly raise crop residue production 10. A positive correlation exists betw...