Pool boiling is an effective heat dissipation approach in electronic cooling, battery thermal management, etc. This study used the electrochemical deposition method to fabricate one smooth nickel specimen (named Ni-smooth) and three specimens with a porous nickel-stacked structure. The three porous specimens were created with deposition current densities of 0.5 A·cm<sup>-2</sup> (named Ni-0.5), 2.0 A·cm<sup>-2</sup> (names Ni-2.0), and 5.0 A·cm<sup>-2</sup> (named Ni-5.0), respectively. The four samples underwent microstructural characterization via scanning electron microscopy. The increasing current density led to the porous nickel surface exhibiting a more distinct pore structure, and the nickel sphere grains became more refined, developing a loose "mound-like" structure. A marked increase in the nickel film thickness was also observed. Through visual experiments, we evaluated their wettability, and through pool-boiling experiments, we tested their boiling heat-transfer properties. Our findings suggest that samples incorporating a porous nickel structure consistently outperform unmodified samples regarding heat-transfer efficiency. Specifically, sample Ni-0.5A demonstrated the most optimal boiling heat-transfer performance, evidenced by a 32.2% reduction in temperature at the onset of boiling, a 19.9% increase in critical heat flux density, and a 78.6% larger maximum heat-transfer coefficient compared to the smooth nickel sample. These marked improvements are intrinsically linked to the specific characteristics of the porous nickel structure. The higher performance of samples Ni-0.5 can be attributed to the presence of additional nucleation sites within the porous structure and the formation of smaller micro-crystalline dendritic constructs due to the specific current density applied during electrodeposition. Understanding this relationship between surface characteristics and electrodeposition is essential in maximizing heat-transfer efficiency.