Biomimetic oxidation of 21-hydroxy, 21-formyl and 21-carboxylic pregn-4-en-3,20-dione with chemical cytochrome P450 model systems

TAKU NAKANO, TEDDY G. TRAYLOR, and DAVID DOLPHIN. Can. J. Chem. 68, 1504Chem. 68, (1990.During the epoxidation of ethylene using iron meso-tetrakis(2,6-dichloropheny1)porphyrin chloride and iodosopentafluorobenzene several N-alkylporphyrins were formed. The major product was 21-carboxymethyl-5,10,15,20-tetrakis(2,6-dichloropheny1)porphyrin. This was derived, by oxidation, from the corresponding 21-formylmethyl complex which in turn was obtained from the initially formed N-hydroxyethylporphyrin, a compound not isolated due to its ready oxidation.

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Biomimetic oxidation of 21-hydroxy, 21-formyl and 21-carboxylic pregn-4-en-3,20-dione with chemical cytochrome P450 model systems

Cited by 4 publications

References 21 publications

Biomimetic oxidation of indole-3-acetic acid and related substrates with hydrogen peroxide catalysed by 5,10,15,20-tetrakis 2′,6′-dichloro-3′-sulfonatophenyl)porphyrinatoiron(III) hydrate in aqueous solution and AOT reverse micelles

Biomimetic oxidation of indole-3-acetic acid and related substrates with hydrogen peroxide catalysed by 5,10,15,20-tetrakis 2′,6′-dichloro-3′-sulfonatophenyl)porphyrinatoiron(III) hydrate in aqueous solution and AOT reverse micelles

Oxidation of 1-naphthol and related phenols with hydrogen peroxide and potassium superoxide catalysed by 5,10,15,20-tetraarylporphyrinatoiron(III)chlorides in different reaction conditions

The formation of N-alkylporphyrins during epoxidation of ethylene catalyzed by iron(III) meso-tetrakis(2,6-dichlorophenyl)porphyrin

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