“…The block copolymerization based on polystyrene with tert-butyl acrylate (tBA), has been reported previously (Coca et al, 1998; Beers et al, 1999; Teodorescu et al, 2000; Min et al, 2005; Pizarro et al, 2013, 2015; Yu et al, 2016), however block copolymers with dimethyl allylmalonate (DMM), and dimethyl itaconate (DMI) as specific monomers were used. To the best of our knowledge, block copolymers with DMM and DMI monomers have not yet been reported.…”