The physical absorption of three Volatile Organic Compounds (dimethyldisulphide (DMDS), dimethylsulphide (DMS) and toluene) in "water/silicone oil" systems at a constant flow rate for mixtures of different compositions (φ = 0, 5, 10, 15, 20 and 100%) was investigated using a dynamic absorption method. The results indicate that silicone oil addition leads to a dramatic decrease in K L a which can be related to the change in the partition coefficient (H mix ). They confirm the results obtained for styrene absorption using another measurement technique [15].The interpretation of the results using dimensionless ratiosversus φ also confirms the importance of the partition coefficient ratio m R = H water /H oil in the K L a change. Moreover, the results obtained for toluene absorption in "air/water/silicone oil" systems (φ = 10, 15 and 20%) suggest that the mass transfer pathway is in the order gas→water→oil for these operating conditions.
Key-wordsAbsorption; Mass Transfer; Hydrophobic VOC; TPPB; Silicone oil