IntroductionOwing to the rapid development of industry, the resulting huge amount of wastewater containing heavy metals has posed a serious challenge to environmental protection. Among heavy metals, cadmium (Cd) is one of the most hazardous materials affecting the environment [1]. As an element of multiple industrial purposes, Cd is widely used in modern industries such as nickel-cadmium batteries, pigments, alloys, phosphate fertilizers, pesticides, textile operations, metal plating, Pol. J. Environ. Stud. Vol. 27, No. 6 (2018), 2851-2859
AbstractImmobilized sulfate-reducing bacteria (SRB) in polyvinyl alcohol (PVA)-sodium alginate matrix were applied as biosorbents to remove cadmium (Cd) from aqueous solutions. Multiple characterization techniques including scanning electron microscope (SEM)-energy dispersive spectrometer (EDS), and Fourier transform infrared (FT-IR) spectra indicate that immobilized beads provided a suitable microenvironment for SRB. Performance tests show that Cd removal was highly affected by pH value and temperature, with optimum temperature at 35ºC and pH value of 8.0. A pseudo second-order model was applied to describe the adsorption kinetic. FT-IR and x-ray photoelectron spectroscopy (XPS) analyses imply that biosorption, sulfide, and hydroxide precipitation are the main mechanisms for removing Cd. The immobilized SRB beads have great potential for remediating Cd-containing wastewater.