2023
DOI: 10.1002/cbic.202300514
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Biotransamination of Furan‐Based Aldehydes with Isopropylamine: Enzyme Screening and pH Influence

Antía Pintor,
Nicoletta Cascelli,
Alexey Volkov
et al.

Abstract: Furan‐based amines are highly valuable compounds which can be directly obtained via reductive amination from easily accessible furfural, 5‐(hydroxymethyl)furfural (HMF) and 2,5‐diformylfuran (DFF). Herein the biocatalytic amination of these carbonyl derivatives is disclosed using amine transaminases (ATAs) and isopropylamine (IPA) as amine donor. Among the different biocatalysts tested, the ones from Chromobacterium violaceum (Cv‐TA), Arthrobacter citreus (ArS‐TA), and variants from Arthrobacter sp. (ArRmut11‐… Show more

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Cited by 5 publications
(1 citation statement)
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“…This parameter offers a DMSO has a beneficial effect on organic substrate solubilities, providing a one-phase system, and its efficiency in enzymatic reactions has been previously proven with many enzyme classes (ADHs, ATAs, etc.) [81][82][83]. Also, the three laccases were previously efficiently tested at high DMSO concentrations, revealing a good stability [84,85].…”
Section: Robustness Of the Assay: Interference Of Side Productsmentioning
confidence: 96%
“…This parameter offers a DMSO has a beneficial effect on organic substrate solubilities, providing a one-phase system, and its efficiency in enzymatic reactions has been previously proven with many enzyme classes (ADHs, ATAs, etc.) [81][82][83]. Also, the three laccases were previously efficiently tested at high DMSO concentrations, revealing a good stability [84,85].…”
Section: Robustness Of the Assay: Interference Of Side Productsmentioning
confidence: 96%