Materials Syntheses
DOI: 10.1007/978-3-211-75125-1_8
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Birnessite-type Manganese Oxide by Redox Precipitation

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Cited by 2 publications
(2 citation statements)
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“…The bond form leaves plenty of dangling bonds at the surface of birnessite, which may act as anchoring sites for IrO 2 nano‐crystals during hydrothermal reaction, as the interlayer distance is wide enough (≈7 Å) that Ir cations can be adsorbed within the birnessite. As observed in our experiments and reported in the literature, the birnessite can be easily prepared at room temperature naturally under oxidizing atmosphere. Thus, it is promising that birnessite forms at first and acts as a growing bed and support material for IrO 2 in the hydrothermal system (illustrated in Figure a).…”
Section: Resultssupporting
confidence: 81%
“…The bond form leaves plenty of dangling bonds at the surface of birnessite, which may act as anchoring sites for IrO 2 nano‐crystals during hydrothermal reaction, as the interlayer distance is wide enough (≈7 Å) that Ir cations can be adsorbed within the birnessite. As observed in our experiments and reported in the literature, the birnessite can be easily prepared at room temperature naturally under oxidizing atmosphere. Thus, it is promising that birnessite forms at first and acts as a growing bed and support material for IrO 2 in the hydrothermal system (illustrated in Figure a).…”
Section: Resultssupporting
confidence: 81%
“…In Method 1, MnO 2 was formed due to the addition of a NaOH and H 2 O 2 mixture (Mixture O) into Mn(NO 3 ) 2 solution as mentioned in Section 2. The formation of MnO 2 can be described as below: 20 Mn 2+ + 2OH − → Mn(OH) 2 Mn(OH) 2 + H 2 O 2 → MnO 2 + 2H 2 O…”
Section: Resultsmentioning
confidence: 99%