Bis(1,3‐dinitratoprop‐2‐yl) Nitramine, a New Sensitive Explosive Combining a Nitrate Ester with a Nitramine

Abstract

International audienceAbstract. Nitro functionalized compounds comprise a large substance class and are the most popular explosive materials. Recent research furnished a solid energetic nitrate ester of potential interest. This work is concerned with the synthesis and characterization of novel aliphatic nitramine compounds with similar feature

Solid‐State and Gas‐Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates

“…Calculations at the Chapman–Jouguet (C‐J) point applied a stationary detonation model with a modified Becker–Kistiakowski–Wilson state equation. The C‐J point was located using the first derivative of the Hugoniot curve of the system . The calculated detonation parameters are comparable with those of glycerine trinitrate (Δ U f 0 −6099 kJ kg −1 , T C‐J 4316 K, P C‐J 23.7 GPa, V det 7850 ms −1 , V o 781 dm 3 kg −1 ).…”

“…TheC-J point was located using the first derivative of the Hugoniot curve of the system. [31] Thec alculated detonation parameters are comparable with those of glycerine trinitrate (DU f 0 À6099 kJ kg À1 , T C-J 4316 K, P C-J 23.7 GPa, V det 7850 ms À1 , V o 781 dm 3 kg À1 ). Theh eat of detonation, detonation pressure,v elocity,a nd temperature of glycerine trinitrate are all higher than those of MN and FMN,b ut the gas volumes released from MN and FMN are smaller.…”

Polynitro Containing Energetic Materials based on Carbonyldiisocyanate and 2, 2‐Dinitropropane‐1, 3‐diol

“…The detonation parameters were calculated at the CJ point with the aid of the steady‐state detonation model using a modified Becker‐Kistiakowski‐Wilson equation of state for modeling the system. The CJ point is found from the Hugoniot curve of the system by its first derivative 23,24. The specific impulses were also calculated with the EXPLO5 V6.01 program, assuming an isobaric combustion of a composition of 70 % oxidizer, 16 % aluminum as fuel, 6 % polybutadiene acrylic acid, 6 % polybutadiene acrylonitrile as binder, and 2 % bisphenol‐A ether as epoxy curing agent 17.…”

Multiply Nitrated High‐Energy Dense Oxidizers Derived from the Simple Amino Acid Glycine

“…24 The detonation parameters were calculated at the CJ point with the aid of the steady‐state detonation model by using a modified Becker–Kistiakowski–Wilson equation of state for modeling the system. The CJ point was determined from the first derivative of the Hugoniot curve of the system 24–25. The specific impulses were also calculated by using the EXPLO5 V5.05 program, assuming the isobaric combustion of a composition of 70 % oxidizer, 16 % aluminum as the fuel, 6 % polybutadiene acrylic acid, 6 % polybutadiene acrylonitrile as a binder, and 2 % bisphenol‐A as the epoxy‐curing agent 20.…”