Bis(2-phenylethylammonium) tetrachloridocobaltate(II)

Oh, In‐Hwan; Kim, D.; Huh, Young‐Duk; Park, Y.; Park, J.M.S.; Park, S.-H.

doi:10.1107/s1600536811011603

Cited by 9 publications

(4 citation statements)

References 12 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For each phenylethylammonium group there are six coplanar atoms forming the mean planes C3C4C5C6C7C8 and C11C12C13C14C15C16 their deviation from the mean plans is ±0,0023 Å, with a dihedral angle between the two planes of 71,27°. Examination of the 2phenylethylammonium cation shows that the bond distances and angles show no significant difference from those obtained in other simple salts involving the same organic groups namely, 2-phenylethylammonium p-hydroxybenzoate [35], bis (2-phenylethylammonium) hexachloridostannate(IV) [36] and Bis(2-phenylethylammonium) tetrachloridocobaltate(II) [37]. The C-N bond lengths are 1.472 (3) [38,39] of types N-H…O and C-H…O involve oxygen atoms of the chromate anions as acceptors, and the protonated nitrogen atoms and carbon atoms of 2-phenylethylammonium as donors.…”

Section: Structure Descriptionmentioning

confidence: 81%

Synthesis and physic-chemical properties of a novel chromate compound with potential biological applications, bis(2-phenylethylammonium) chromate(VI)

Trabelsi

Issaoui

Brandán

et al. 2019

Journal of Molecular Structure

View full text Add to dashboard Cite

The structure of bis(2-phenylethylammonium) chromate(VI) (2phCr) was determined from X-ray diffraction data. The compound crystallizes in the monoclinic system (space group C2/c) with the lattice parameters: a = 38.136(2) Å, b = 11.2334(6) Å, c = 8.1643(4) Å; β = 98.480(2) V= 3459.3(3) Å 3 and Z = 8. The structure was solved from 3358 independent reflections with R = 0.034 and Rw = 0.1089. The structure consists of discrete anions (CrO 4 2-) stacked in layers parallel to (b, c) plane at x = 1/4 and 3/4. These anions are connected to the 2-phenylethylammonium cations through N-H…O and C-H…O hydrogen bonds, forming a two-dimensional arrangement. Crystal structure and spectroscopic studies are reported for the 2phCr. In addition, Hirshfeld surfaces and two-dimensional fingerprint plots estimate the intermolecular interactions accountable for the generation of crystal packing. Furthermore, the title compound was screened for antibacterial activities against five pathogenic strains namely: Escherichia coli ATCC 8739, Salmonella typhimurium ATCC 14028, Staphylococus aureus ATCC 6538, Enterococcus feacium ATCC 19434 and Streptocoque B (Sreptococcus agalactiae) and antifungal activities against a clinical strain called Candida albicans ATCC 10231, corroborating significant activity. In silico investigation of bioactivity of 2phCr was performed via molecular docking analysis with four types of secreted aspartic proteinases (SAP, SAP1, SAP3, and SAP5) from Candida albicans to explore the antifungal properties in comparison to behavior of known antifungals used to treat Candida albicans, and with three types of β-ketoacyl acyl carrier protein synthase enzymes (KAS I (FabB), KAS II (FabF) and KAS III (FabH)) from Escherichia coli in comparison with that of aminothiazole, thilactomycin, and cerulerin antimicrobials. In addition, the complete assignments for 2phCr are reported considering monodentate coordination for the chromate group.

show abstract

Section: Structure Descriptionmentioning

confidence: 81%

Synthesis and physic-chemical properties of a novel chromate compound with potential biological applications, bis(2-phenylethylammonium) chromate(VI)

Trabelsi

Issaoui

Brandán

et al. 2019

Journal of Molecular Structure

View full text Add to dashboard Cite

show abstract

“…To prepare an adequate low-dimensional magnetic material, where the interlayer distance has a signi cant in uence on the magnetic properties, organic molecules are used. This research interest leads to the synthesis of the series of inorganic-organic layered materials [3,4]. The title compound shows a layered structure in which Mn(H 2 O) 6 inorganic layers are located between the organic (anion of "methyl orange") bilayers.…”

Section: Discussionmentioning

confidence: 99%

Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C₂₈H₄₀MnN₆O₁₂S₂

Park

2016

Zeitschrift Für Kristallographie - New Crystal Structures

Self Cite

View full text Add to dashboard Cite

C 28 H 40 MnN 6 O 12 S 2 , monoclinic, P21/c (no. 14), a = 6.211(5) Å, CCDC no.: 1446507The crystal structure is shown in the gure. Tables 1-3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Source of materialMnCl 2 . 4H 2 O (0.2976 g) was added to a solution of C14H14N 3 NaO 3 S (0.491 g) in methanol (200 mL) and the mixture was slowly evaporated. Small red-brown crystals were obtained approximately after a week. Experimental detailsAll H atoms were located in a di erence Fourier map. Carbon-bound hydrogen atoms are riding on the parent atom, whereas the oxygen-bound hydrogen atom positions are re ned. H atoms at methyl group were re ned with U iso (H) = 1.5Ueq(C).

show abstract

“…To overcome this hurdle, we have conducted many experiments and finally we have been able to synthesize a series of layered inorganic-organic hybrid perovskite crystals using phenylethylammonium cations. Among others, the crystal structures of (C 6 H 5 CH 2 CH 2 NH 3 ) 2 CoCl 4 (Co-PEA), (C 6 H 5 CH 2 CH 2 NH 3 ) 2 MnCl 4 (Mn-PEA) and (C 6 H 5 CH 2 CH 2 NH 3 ) 2 CuCl 4 (Cu-PEA) have been solved by the X-ray single crystal diffraction technique [5][6][7]. Co-PEA crystallizes in a monoclinic space group P12 1 /c1 (No.…”

Section: Introductionmentioning

confidence: 99%

Magnetic Structure of Inorganic–Organic Hybrid (C6H5CH2CH2NH3)2MnCl4 Using Magnetic Space Group Concept

Park

et al. 2020

Symmetry

Self Cite

View full text Add to dashboard Cite

Previously, we reported that inorganic–organic hybrid (C6H5CH2CH2NH3)2MnCl4 (Mn-PEA) is antiferromagnetic below 44 K by using magnetic susceptibility and neutron diffraction measurements. Generally, when an antiferromagnetic system is investigated by the neutron diffraction method, half-integer forbidden peaks, which indicate an enlargement of the magnetic cell compared to the chemical cell, should be present. However, in the case of the title compound, integer forbidden peaks are observed, suggesting that the size of the magnetic cell is the same as that of the chemical cell. This phenomenon was until now only theoretically predicted. During our former study, using an irreducible representation method, we suggested that four spin arrangements could be possible candidates and a magnetic cell and chemical cell should coincide. Recently, a magnetic structure analysis employing a magnetic space group has been developed. To confirm our former result by the representation method, in this work we employed a magnetic space group concept, and from this analysis, we show that the magnetic cell must coincide with the nuclear cell because only the Black–White 1 group (equi-translation or same translation group) is possible.

show abstract

Bis(2-phenylethylammonium) tetrachloridocobaltate(II)

Abstract: Acta Cryst. (2011). E67, m522-m523 Oh et al. (C 8 H 12 N) 2 [CoCl 4 ] m523 supporting information sup-1

Cited by 9 publications

References 12 publications

Synthesis and physic-chemical properties of a novel chromate compound with potential biological applications, bis(2-phenylethylammonium) chromate(VI)

Synthesis and physic-chemical properties of a novel chromate compound with potential biological applications, bis(2-phenylethylammonium) chromate(VI)

Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C₂₈H₄₀MnN₆O₁₂S₂

Magnetic Structure of Inorganic–Organic Hybrid (C6H5CH2CH2NH3)2MnCl4 Using Magnetic Space Group Concept

Contact Info

Product

Resources

About

Bis(2-phenylethylammonium) tetrachloridocobaltate(II)

Abstract: Acta Cryst. (2011). E67, m522-m523 Oh et al. (C 8 H 12 N) 2 [CoCl 4 ] m523 supporting information sup-1

Cited by 9 publications

References 12 publications

Synthesis and physic-chemical properties of a novel chromate compound with potential biological applications, bis(2-phenylethylammonium) chromate(VI)

Synthesis and physic-chemical properties of a novel chromate compound with potential biological applications, bis(2-phenylethylammonium) chromate(VI)

Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C28H40MnN6O12S2

Magnetic Structure of Inorganic–Organic Hybrid (C6H5CH2CH2NH3)2MnCl4 Using Magnetic Space Group Concept

Contact Info

Product

Resources

About

Crystal structure of hexaaquamanganese(II) bis((E)-4-((4-(dimethylamino)phenyl)diazenyl)benzenesulfonate), C₂₈H₄₀MnN₆O₁₂S₂