[Bis(2-pyridylmethyl)amine]dichloridomercury(II)

Kim, Young-Inn; Lee, You-Soon; Seo, Hoe-Joo; Nam, Ki-Sun; Kang, Sung Kwon

doi:10.1107/s1600536808000858

Cited by 6 publications

(1 citation statement)

References 10 publications

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“…Hence, the coordination environment is strongly distorted, irrespective of the underlying geometry. A related compound featuring two chlorido ligands instead of the more spacious trifluoroacetato ligands has been reported to adopt a similar geometry 11…”

Section: Resultsmentioning

confidence: 99%

N‐Methyl‐2, 2'‐Dipicolylamine Complexes as Potential Models for Metal‐Mediated Base Pairs

Seubert

Böhme

Kösters

et al. 2012

Zeitschrift anorg allge chemie

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Metal-mediated base pairs can be used to insert metal ions into nucleic acids at precisely defined positions. As structural data on the resulting metal-modified DNA are scarce, appropriate model complexes need to be synthesized and structurally characterized. Accordingly, the molecular structures of nine transition metal complexes of N-methyl-2,2'-dipicolylamine (dipic) are reported. In combination with an azole-containing artificial nucleoside, this tridentate ligand had recently been used to generate metal-mediated base pairs (Chem. Commun. 2011, 47, 11041-11043). The Pd II and Pt II complexes reported

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Section: Resultsmentioning

confidence: 99%

N‐Methyl‐2, 2'‐Dipicolylamine Complexes as Potential Models for Metal‐Mediated Base Pairs

Seubert

Böhme

Kösters

et al. 2012

Zeitschrift anorg allge chemie

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Structural diversity of Zn(ii)/Cd(ii) complexes based on bis(pyridyl) ligands with a long flexible spacer: From zero-dimensional binuclear, one-dimensional chain, two-dimensional layer, to three-dimensional frameworks

Deng

Huo

et al. 2011

CrystEngComm

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[Benzyl(2-pyridylmethyl)amine]dichloridomercury(II)

et al. 2008

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The Hg atom in the title compound, [HgCl2(C13H14N2)], adopts a distorted tetrahedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmethyl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl—Hg—Cl atoms is 85.4 (1)°. The phenyl ring on the bpma ligand is twisted out of the pyridine plane, forming a dihedral angle of 76.0 (3)°. Disorder in this ring is also noted with two coplanar conformations having equal site occupancies.

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[Bis(2-pyridylmethyl)amine]dichloridomercury(II)

Cited by 6 publications

References 10 publications

N‐Methyl‐2, 2'‐Dipicolylamine Complexes as Potential Models for Metal‐Mediated Base Pairs

N‐Methyl‐2, 2'‐Dipicolylamine Complexes as Potential Models for Metal‐Mediated Base Pairs

Structural diversity of Zn(ii)/Cd(ii) complexes based on bis(pyridyl) ligands with a long flexible spacer: From zero-dimensional binuclear, one-dimensional chain, two-dimensional layer, to three-dimensional frameworks

[Benzyl(2-pyridylmethyl)amine]dichloridomercury(II)

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