Bis(acetylacetonato-κ²O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)

Abstract

In the title complex, [Mn(C5H7O2)2(NCS)(CH4O)], the MnIII atom has a slightly distorted octa­hedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetyl­acetonate ligands, while the axial positions are occupied by the N atom of the thio­cyanate anion and the O atom of the methanol mol­ecule. In the crystal structure, complex mol­ecules are linked by an inter­molecular O—H⋯S hydrogen bond, forming a chain running along [101].