Bis[benzylN′-(3-phenylprop-2-enylidene)hydrazinecarbodithioato-κ²N′,S]zinc(II)

Abstract

Fun et al. [Zn(C 17 H 15 N 2 S 2) 2 ] m519

Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate

“…The bond lengths and angles are in normal ranges (Allen et al, 1987). However the C═S distance of 1.7466 (17) Å is longer than the typical value of dithiocarbazate derivatives (Crouse et al, 2004;Fun et al, 2008;Shanmuga Sundara Raj et al, 2000) but being intermediate between the values of 1.82 Å for a C-S single bond and 1.56 Å for a C═S double bond (Suton, 1965). The C9-N2 distance of 1.285 (2) Å indicates a double bond charactor.…”

“…For information on values of bond lengths, see Allen et al (1987). For related structures of dithiocarbazate derivatives, see, for example: Crouse et al (2004); Fun et al (2008); Shanmuga Sundara Raj et al (2000). For applications and bioactivities of dithiocarbazate derivatives, see, for example: Ali & Tarafder (1977); Ali et al (2001Ali et al ( , 2002Ali et al ( , 2008; Chan et al (2008); Chew et al (2004); Crouse et al (2004); Tarafder et al (1978Tarafder et al ( , 1981Tarafder et al ( , 2001Tarafder et al ( , 2008.…”

Bis[benzyl 3-(3-phenylprop-2-enylidene)dithiocarbazato-κ2N3,S]cadmium

“…For the structure of uncoordinated Schiff bases, see ;. For the isotypic Zn and Hg analogues, see: Fun et al (2008); Islam et al (2012). For the coordination behaviour of metal ions (Co, Ni, Cu, Zn, Cd and Hg) with the cinnamaldehyde Schiff base of S-methyldithiocarbazate, see: Liu et al (2009); Abram et al (2006).…”

“…The two chelating five-membered rings form a dihedral angle of 84.01 (9)°. Since the structure is isotypic with those of Zn (Fun et al, 2008) and Hg (Islam et al, 2012), it is worthwhile to compare the geometries around the metal ions. The M-N bond lengths in the series follow the trend Zn < Cd < Hg (2.0662 (12), 2.306 (2), 2.489 (3) Å) in agreement with the respective ionic radii.…”