Bis[bis(diphenylthiophosphinyl)amido-κ²S,S′]platinum(II)

Abstract

Key indicators: single-crystal X-ray study; T = 296 K; mean (C-C) = 0.008 Å; disorder in main residue; R factor = 0.026; wR factor = 0.066; data-to-parameter ratio = 16.7.In the title compound, [Pt(C 24 H 20 NP 2 S 2 ) 2 ], the Pt atom is in a distorted square-planar environment and contains two sixmembered carbon-free chelate rings, one in twist-boat and the other in a half-chair conformation. Two phenyl groups are disordered over two set of sites in ratios of 0.721 (13):0.279 (13) and 0.71 (7):0.29 (7). Related literature