2012
DOI: 10.1107/s1600536812028942
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Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate

Abstract: In the cation of the title compound, [Cu(C2H8N2)2(CH3OH)2](C8H4O4)·2CH3OH, the CuII atom lies on an inversion centre. The four N atoms of two ethyl­enediamine ligands around the CuII atom form the equatorial plane, while two methanol O atoms in the axial positions complete a Jahn–Teller distorted octa­hedral coordination. The benzene-1,4-dicarboxyl­ate anion is centrosymmetric. In the crystal, C—H⋯O, N—H⋯O and O—H⋯O hydrogen bonds link the cations, the anions and the methanol solvent mol­ecules.

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