Bis(tetra-n-butylammonium) bis(5,6-dicyanopyrazine-2,3-dithiolato-κ2
 S,S′)nickelate(II)

Tomura, Masaaki

doi:10.1107/s2414314617010598

Cited by 2 publications

(2 citation statements)

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“…(Figure 5b, Table S16). The average bond length M-S value (2.175 Å), found in the acceptor, indicates that the complex is in a dianionic state [36]. The nickel dianion presents a slight chair type distortion, and the ET molecule shows the usual geometry found in other related salts of this donor (Figure 5b) [37].…”

Section: (A)mentioning

confidence: 87%

Synthesis and Characterization of Charge Transfer Salts Based on [M(dcdmp)2] (M = Au, Cu and Ni) with TTF Type Donors

et al. 2018

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The charge transfer salts α-DT-TTF[Au(dcdmp) 2 ] (1), BET-TTF[Au(dcdmp) 2 ] (2M and 2T), α-DT-TTF[Cu(dcdmp) 2 ] (3), ET[Cu(dcdmp) 2 ] (4), (BET-TTF) 2 [Cu(dcdmp) 2 ] (5), (ET) 2 [Ni(dcdmp) 2 ] (6), and α-mtdt[Cu(dcdmp) 2 ] (7) were obtained by electrocrystallization of different electron donor molecules derived from TTF (α-DT-TTF = alpha-dithiophene-tetrathiafulvalene; BET-TTF = (bis(ethylenethio)tetrathiafulvalene; ET = bis(ethylenedithio)-tetrathiafulvalene; α-mtdt = alpha-methylthiophenetetrathiafulvalene) in the presence of transition metal complex [M(dcdmp) 2 ] (M = Au (III), Cu (III) and Ni (II)) (dcdmp = 2,3-dicyano-5,6-dimercaptopyrazine). Compounds 1 and 2 (2M and 2T) have a similar packing pattern composed of mixed stacks of alternating donor-acceptor molecules. For (BET-TTF)[Au(dcdmp) 2 ] two different crystal structures (2M and 2T) were obtained indicating polymorphism. Compounds 3 and 4 are isostructural being composed of zigzag chains of alternating donor and acceptor molecules. The salts with a 2:1 stoichiometry, (BET-TTF) 2 [Cu(dcdmp) 2 ] (5), and (ET) 2 [Ni(dcdmp) 2 ] (6) present the donor molecules fully oxidized and [M(dcdmp) 2 ] (M = Ni and Cu) in a dianionic state. The salt of the dissymmetric donor α-mtdt with [Cu(dcdmp) 2 ], α-mtdt[Cu(dcdmp) 2 ] (7) has a crystal structure composed of segregated donor stacks that are positioned in a head-to-head fashion and alternate with the anion stacks. All charge transfer salts (1-7) are modest semiconductors with conductivities in the range 10 −1-10 −5 S/cm, with the highest values obtained in α-DT-TTF salts, compounds 1 and 3.

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Section: (A)mentioning

confidence: 87%

Synthesis and Characterization of Charge Transfer Salts Based on [M(dcdmp)2] (M = Au, Cu and Ni) with TTF Type Donors

et al. 2018

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“…Compared to the abundance of the female, the male of N. yamanei is rarely collected. Some females were found above the ground surface (1 m or more) ( Nagase 1995 ; Tomura 2020 ), but in fact they are more likely on the ground floor or in the leaf litter. Multiple females were obtained in Malaise traps, suggesting that females actively walk around the forest floor and climb understory vegetation.…”

Section: Taxonomic Accountmentioning

confidence: 99%

Taxonomic study of Baeosega and its allies, with description of a new species of Nipponosega (Hymenoptera, Chrysididae, Amiseginae)

Mita

2021

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Three related genera of Asian Amiseginae, Baeosega Krombein, Nipponosega Kurzenko & Lelej, and Okinawasega Terayama are revised. The male of N. yamanei Kurzenko & Lelej and the female of O. eguchii Terayama are newly described. The following new synonymies are proposed: Baeosega humida Krombein, 1984 = B. laticeps Krombein, 1984, syn. nov.; Nipponosega yamanei Kurzenko & Lelej, 1994 = N. kantoensis Nagase, 1995, syn. nov. A new species of Nipponosega, N. lineatasp. nov. is described based on a female from Thailand. A key to genera and species of Baeosega, Nipponosega and Okinawasega is given.

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Bis(tetra-n-butylammonium) bis(5,6-dicyanopyrazine-2,3-dithiolato-κ² S,S′)nickelate(II)

Cited by 2 publications

References 10 publications

Synthesis and Characterization of Charge Transfer Salts Based on [M(dcdmp)2] (M = Au, Cu and Ni) with TTF Type Donors

Synthesis and Characterization of Charge Transfer Salts Based on [M(dcdmp)2] (M = Au, Cu and Ni) with TTF Type Donors

Taxonomic study of Baeosega and its allies, with description of a new species of Nipponosega (Hymenoptera, Chrysididae, Amiseginae)

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Bis(tetra-n-butylammonium) bis(5,6-dicyanopyrazine-2,3-dithiolato-κ2 S,S′)nickelate(II)

Cited by 2 publications

References 10 publications

Synthesis and Characterization of Charge Transfer Salts Based on [M(dcdmp)2] (M = Au, Cu and Ni) with TTF Type Donors

Synthesis and Characterization of Charge Transfer Salts Based on [M(dcdmp)2] (M = Au, Cu and Ni) with TTF Type Donors

Taxonomic study of Baeosega and its allies, with description of a new species of Nipponosega (Hymenoptera, Chrysididae, Amiseginae)

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Bis(tetra-n-butylammonium) bis(5,6-dicyanopyrazine-2,3-dithiolato-κ² S,S′)nickelate(II)