Bis(tri-tert-butoxysilanethiolato-κS)bis(pyrrolidine-κN)cobalt(II)

Abstract

Key indicatorsSingle-crystal X-ray study T = 120 K Mean (C-C) = 0.003 Å Disorder in main residue R factor = 0.039 wR factor = 0.097 Data-to-parameter ratio = 16.6For details of how these key indicators were automatically derived from the article, see

Novel tetrahedral cobalt(ii) silanethiolates: structures and magnetism

“…smaller than those observed in 1 and do not inuence the Co-N as well as Co-S bond distances which still are comparable with those found in other tetrahedral Co(II) silanethiolate complexes. 15,30 Co(II) cores are bridged by the piperazine molecule separating them apart at 6.041(1)Å distance. Recently, we have described another binuclear and tetrahedral Co(II) silanethiolate [Co{SSi(tBuO) 3 } 2 (m-3AMP)] 2 bridged by 3-aminomethylpyridine with metallic centers distanced at 6.483(3)Å.…”