2005
DOI: 10.1016/j.jfluchem.2005.05.002
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Bis(trifluoromethyl)dicarbonate, CF3OC(O)OC(O)OCF3

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Cited by 7 publications
(3 citation statements)
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“…In particular, for the fluorosulfate FS(O 2 )O radical, several experimental and theoretical kinetic investigations have been reported [13][14][15][16][17][18][19][20][21][22]. Interesting compounds could be generated by association reactions between these radicals [23][24][25]. In fact, the FC(O)OOO(O)CF is formed as a byproduct in the thermal reaction between F 2 and CO in the presence of O 2 [26,27].…”
Section: Introductionmentioning
confidence: 99%
“…In particular, for the fluorosulfate FS(O 2 )O radical, several experimental and theoretical kinetic investigations have been reported [13][14][15][16][17][18][19][20][21][22]. Interesting compounds could be generated by association reactions between these radicals [23][24][25]. In fact, the FC(O)OOO(O)CF is formed as a byproduct in the thermal reaction between F 2 and CO in the presence of O 2 [26,27].…”
Section: Introductionmentioning
confidence: 99%
“…It is interesting to note that the “typical” values are not followed by CF 3 C(O)OONO 2 . We believe that the lack of the O atom next to CO is responsible for this behavior as has been discussed elsewhere 4 NMR Chemical Shifts (ppm) and Coupling Constants (Hz) for CF 3 OC(O)OONO 2 and Related Compounds compound CF 3 OC(O)OONO 2 FC(O)OONO 2 CF 3 C(O)OONO 2 CF 3 OC(O)OOC(O)F ref this work 13 14 31 δ C (CF 3 ) 119.1 115.0 119.9 δ C (CO) 145.8 144.8 155.4 144.8 δ F (CF 3 ) −58.4 (−32.2) −73.9 −59,7 1 J CF 270.0 (307.0) 286.0 268.0 2 J CF 45.8 3 J CF 2.3 conditions a −30 °C, int −30 °C, ext −30 °C, ext a Abbreviations are as follows: int is a sample solved in lock CD 2 Cl 2 ( 13 C δ = 54.0) with a few percent of CFCl 3 ( 19 F δ = 0.0) and ext is a neat sample external lock and standard. …”
Section: Resultsmentioning
confidence: 72%
“…The reactions of these radicals with O 2 and CO lead to the family of radicals CF 3 O x , CF 3 CO x , FCO x , and CF 3 OCO x , from which it is possible to obtain new species. The study of these reactions afforded new compounds to be synthesized and used as precursors of atmospherically relevant radicals which were thus isolated. …”
Section: Introductionmentioning
confidence: 99%